TY - JOUR
T1 - X-ray structure and properties of a cyclo[6]pyrrole[3]thiophene
AU - Bui, Thanh Tuan
AU - Escande, Aude
AU - Philouze, Christian
AU - Cioci, Gianluca
AU - Ghosh, Sudip
AU - Saint-Aman, Eric
AU - Lim, Jong Min
AU - Moutet, Jean Claude
AU - Sessler, Jonathan L.
AU - Kim, Dongho
AU - Bucher, Christophe
PY - 2013
Y1 - 2013
N2 - A new member of the cyclo[n]pyrrole class of expanded porphyrins was prepared from the corresponding thiophene-containing terpyrrole precursor through use of a mild electrochemical oxidative procedure. The isolated macrocycle, featuring nine heterocyclic subunits directly connected through their α,α′-positions, is the largest cyclo[n]pyrrole derivative reported to date. The structure obtained via synchrotron radiation-based studies revealed a dimeric arrangement involving individual macrocyclic subunits.
AB - A new member of the cyclo[n]pyrrole class of expanded porphyrins was prepared from the corresponding thiophene-containing terpyrrole precursor through use of a mild electrochemical oxidative procedure. The isolated macrocycle, featuring nine heterocyclic subunits directly connected through their α,α′-positions, is the largest cyclo[n]pyrrole derivative reported to date. The structure obtained via synchrotron radiation-based studies revealed a dimeric arrangement involving individual macrocyclic subunits.
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U2 - 10.1142/S1088424612501325
DO - 10.1142/S1088424612501325
M3 - Article
AN - SCOPUS:84874171759
SN - 1088-4246
VL - 17
SP - 27
EP - 35
JO - Journal of Porphyrins and Phthalocyanines
JF - Journal of Porphyrins and Phthalocyanines
IS - 1-2
ER -