X-ray Free Electron Laser-Induced Synthesis of ϵ-Iron Nitride at High Pressures

Huijeong Hwang; Taehyun Kim; Hyunchae Cynn; Thomas Vogt; Rachel J. Husband; Karen Appel; Carsten Baehtz; Orianna B. Ball; Marzena A. Baron; Richard Briggs; Maxim Bykov; Elena Bykova; Valerio Cerantola; Julien Chantel; Amy L. Coleman; Dana Dattlebaum; Leora E. Dresselhaus-Marais; Jon H. Eggert; Lars Ehm; William J. Evans; Guillaume Fiquet; Mungo Frost; Konstantin Glazyrin; Alexander F. Goncharov; Zsolt Jenei; Jaeyong Kim; Zuzana Konôpková; Jona Mainberger; Mikako Makita; Hauke Marquardt; Emma E. McBride; James D. McHardy; Sébastien Merkel; Guillaume Morard; Earl F. O'Bannon; Christoph Otzen; Edward J. Pace; Alexander Pelka; Charles M. Pépin; Jeffrey S. Pigott; Vitali B. Prakapenka; Clemens Prescher; Ronald Redmer; Sergio Speziale; Georg Spiekermann; Cornelius Strohm; Blake T. Sturtevant; Nenad Velisavljevic; Max Wilke; Choong Shik Yoo; Ulf Zastrau; Hanns Peter Liermann; Malcolm I. McMahon; R. Stewart McWilliams; Yongjae Lee

doi:10.1021/acs.jpclett.1c00150

X-ray Free Electron Laser-Induced Synthesis of ϵ-Iron Nitride at High Pressures

Huijeong Hwang, Taehyun Kim, Hyunchae Cynn, Thomas Vogt, Rachel J. Husband, Karen Appel, Carsten Baehtz, Orianna B. Ball, Marzena A. Baron, Richard Briggs, Maxim Bykov, Elena Bykova, Valerio Cerantola, Julien Chantel, Amy L. Coleman, Dana Dattlebaum, Leora E. Dresselhaus-Marais, Jon H. Eggert, Lars Ehm, William J. EvansGuillaume Fiquet, Mungo Frost, Konstantin Glazyrin, Alexander F. Goncharov, Zsolt Jenei, Jaeyong Kim, Zuzana Konôpková, Jona Mainberger, Mikako Makita, Hauke Marquardt, Emma E. McBride, James D. McHardy, Sébastien Merkel, Guillaume Morard, Earl F. O'Bannon, Christoph Otzen, Edward J. Pace, Alexander Pelka, Charles M. Pépin, Jeffrey S. Pigott, Vitali B. Prakapenka, Clemens Prescher, Ronald Redmer, Sergio Speziale, Georg Spiekermann, Cornelius Strohm, Blake T. Sturtevant, Nenad Velisavljevic, Max Wilke, Choong Shik Yoo, Ulf Zastrau, Hanns Peter Liermann, Malcolm I. McMahon, R. Stewart McWilliams, Yongjae Lee

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18 Citations (Scopus)

Abstract

The ultrafast synthesis of ϵ-Fe3N1+x in a diamond-anvil cell (DAC) from Fe and N2 under pressure was observed using serial exposures of an X-ray free electron laser (XFEL). When the sample at 5 GPa was irradiated by a pulse train separated by 443 ns, the estimated sample temperature at the delay time was above 1400 K, confirmed by in situ transformation of α- to γ-iron. Ultimately, the Fe and N2 reacted uniformly throughout the beam path to form Fe3N1.33, as deduced from its established equation of state (EOS). We thus demonstrate that the activation energy provided by intense X-ray exposures in an XFEL can be coupled with the source time structure to enable exploration of the time-dependence of reactions under high-pressure conditions.

Original language	English
Pages (from-to)	3246-3252
Number of pages	7
Journal	Journal of Physical Chemistry Letters
Volume	12
Issue number	12
DOIs	https://doi.org/10.1021/acs.jpclett.1c00150
Publication status	Published - 2021 Apr 1

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Publisher Copyright:
©

All Science Journal Classification (ASJC) codes

General Materials Science
Physical and Theoretical Chemistry

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10.1021/acs.jpclett.1c00150

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Hwang, H., Kim, T., Cynn, H., Vogt, T., Husband, R. J., Appel, K., Baehtz, C., Ball, O. B., Baron, M. A., Briggs, R., Bykov, M., Bykova, E., Cerantola, V., Chantel, J., Coleman, A. L., Dattlebaum, D., Dresselhaus-Marais, L. E., Eggert, J. H., Ehm, L., ... Lee, Y. (2021). X-ray Free Electron Laser-Induced Synthesis of ϵ-Iron Nitride at High Pressures. Journal of Physical Chemistry Letters, 12(12), 3246-3252. https://doi.org/10.1021/acs.jpclett.1c00150

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title = "X-ray Free Electron Laser-Induced Synthesis of ϵ-Iron Nitride at High Pressures",

abstract = "The ultrafast synthesis of ϵ-Fe3N1+x in a diamond-anvil cell (DAC) from Fe and N2 under pressure was observed using serial exposures of an X-ray free electron laser (XFEL). When the sample at 5 GPa was irradiated by a pulse train separated by 443 ns, the estimated sample temperature at the delay time was above 1400 K, confirmed by in situ transformation of α- to γ-iron. Ultimately, the Fe and N2 reacted uniformly throughout the beam path to form Fe3N1.33, as deduced from its established equation of state (EOS). We thus demonstrate that the activation energy provided by intense X-ray exposures in an XFEL can be coupled with the source time structure to enable exploration of the time-dependence of reactions under high-pressure conditions.",

author = "Huijeong Hwang and Taehyun Kim and Hyunchae Cynn and Thomas Vogt and Husband, {Rachel J.} and Karen Appel and Carsten Baehtz and Ball, {Orianna B.} and Baron, {Marzena A.} and Richard Briggs and Maxim Bykov and Elena Bykova and Valerio Cerantola and Julien Chantel and Coleman, {Amy L.} and Dana Dattlebaum and Dresselhaus-Marais, {Leora E.} and Eggert, {Jon H.} and Lars Ehm and Evans, {William J.} and Guillaume Fiquet and Mungo Frost and Konstantin Glazyrin and Goncharov, {Alexander F.} and Zsolt Jenei and Jaeyong Kim and Zuzana Kon{\^o}pkov{\'a} and Jona Mainberger and Mikako Makita and Hauke Marquardt and McBride, {Emma E.} and McHardy, {James D.} and S{\'e}bastien Merkel and Guillaume Morard and O'Bannon, {Earl F.} and Christoph Otzen and Pace, {Edward J.} and Alexander Pelka and P{\'e}pin, {Charles M.} and Pigott, {Jeffrey S.} and Prakapenka, {Vitali B.} and Clemens Prescher and Ronald Redmer and Sergio Speziale and Georg Spiekermann and Cornelius Strohm and Sturtevant, {Blake T.} and Nenad Velisavljevic and Max Wilke and Yoo, {Choong Shik} and Ulf Zastrau and Liermann, {Hanns Peter} and McMahon, {Malcolm I.} and McWilliams, {R. Stewart} and Yongjae Lee",

note = "Publisher Copyright: {\textcopyright} ",

year = "2021",

month = apr,

day = "1",

doi = "10.1021/acs.jpclett.1c00150",

language = "English",

volume = "12",

pages = "3246--3252",

journal = "Journal of Physical Chemistry Letters",

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Hwang, H, Kim, T, Cynn, H, Vogt, T, Husband, RJ, Appel, K, Baehtz, C, Ball, OB, Baron, MA, Briggs, R, Bykov, M, Bykova, E, Cerantola, V, Chantel, J, Coleman, AL, Dattlebaum, D, Dresselhaus-Marais, LE, Eggert, JH, Ehm, L, Evans, WJ, Fiquet, G, Frost, M, Glazyrin, K, Goncharov, AF, Jenei, Z, Kim, J, Konôpková, Z, Mainberger, J, Makita, M, Marquardt, H, McBride, EE, McHardy, JD, Merkel, S, Morard, G, O'Bannon, EF, Otzen, C, Pace, EJ, Pelka, A, Pépin, CM, Pigott, JS, Prakapenka, VB, Prescher, C, Redmer, R, Speziale, S, Spiekermann, G, Strohm, C, Sturtevant, BT, Velisavljevic, N, Wilke, M, Yoo, CS, Zastrau, U, Liermann, HP, McMahon, MI, McWilliams, RS & Lee, Y 2021, 'X-ray Free Electron Laser-Induced Synthesis of ϵ-Iron Nitride at High Pressures', Journal of Physical Chemistry Letters, vol. 12, no. 12, pp. 3246-3252. https://doi.org/10.1021/acs.jpclett.1c00150

TY - JOUR

T1 - X-ray Free Electron Laser-Induced Synthesis of ϵ-Iron Nitride at High Pressures

AU - Hwang, Huijeong

AU - Kim, Taehyun

AU - Cynn, Hyunchae

AU - Vogt, Thomas

AU - Husband, Rachel J.

AU - Appel, Karen

AU - Baehtz, Carsten

AU - Ball, Orianna B.

AU - Baron, Marzena A.

AU - Briggs, Richard

AU - Bykov, Maxim

AU - Bykova, Elena

AU - Cerantola, Valerio

AU - Chantel, Julien

AU - Coleman, Amy L.

AU - Dattlebaum, Dana

AU - Dresselhaus-Marais, Leora E.

AU - Eggert, Jon H.

AU - Ehm, Lars

AU - Evans, William J.

AU - Fiquet, Guillaume

AU - Frost, Mungo

AU - Glazyrin, Konstantin

AU - Goncharov, Alexander F.

AU - Jenei, Zsolt

AU - Kim, Jaeyong

AU - Konôpková, Zuzana

AU - Mainberger, Jona

AU - Makita, Mikako

AU - Marquardt, Hauke

AU - McBride, Emma E.

AU - McHardy, James D.

AU - Merkel, Sébastien

AU - Morard, Guillaume

AU - O'Bannon, Earl F.

AU - Otzen, Christoph

AU - Pace, Edward J.

AU - Pelka, Alexander

AU - Pépin, Charles M.

AU - Pigott, Jeffrey S.

AU - Prakapenka, Vitali B.

AU - Prescher, Clemens

AU - Redmer, Ronald

AU - Speziale, Sergio

AU - Spiekermann, Georg

AU - Strohm, Cornelius

AU - Sturtevant, Blake T.

AU - Velisavljevic, Nenad

AU - Wilke, Max

AU - Yoo, Choong Shik

AU - Zastrau, Ulf

AU - Liermann, Hanns Peter

AU - McMahon, Malcolm I.

AU - McWilliams, R. Stewart

AU - Lee, Yongjae

PY - 2021/4/1

Y1 - 2021/4/1

N2 - The ultrafast synthesis of ϵ-Fe3N1+x in a diamond-anvil cell (DAC) from Fe and N2 under pressure was observed using serial exposures of an X-ray free electron laser (XFEL). When the sample at 5 GPa was irradiated by a pulse train separated by 443 ns, the estimated sample temperature at the delay time was above 1400 K, confirmed by in situ transformation of α- to γ-iron. Ultimately, the Fe and N2 reacted uniformly throughout the beam path to form Fe3N1.33, as deduced from its established equation of state (EOS). We thus demonstrate that the activation energy provided by intense X-ray exposures in an XFEL can be coupled with the source time structure to enable exploration of the time-dependence of reactions under high-pressure conditions.

AB - The ultrafast synthesis of ϵ-Fe3N1+x in a diamond-anvil cell (DAC) from Fe and N2 under pressure was observed using serial exposures of an X-ray free electron laser (XFEL). When the sample at 5 GPa was irradiated by a pulse train separated by 443 ns, the estimated sample temperature at the delay time was above 1400 K, confirmed by in situ transformation of α- to γ-iron. Ultimately, the Fe and N2 reacted uniformly throughout the beam path to form Fe3N1.33, as deduced from its established equation of state (EOS). We thus demonstrate that the activation energy provided by intense X-ray exposures in an XFEL can be coupled with the source time structure to enable exploration of the time-dependence of reactions under high-pressure conditions.

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UR - http://www.scopus.com/inward/citedby.url?scp=85103683725&partnerID=8YFLogxK

U2 - 10.1021/acs.jpclett.1c00150

DO - 10.1021/acs.jpclett.1c00150

M3 - Article

C2 - 33764078

AN - SCOPUS:85103683725

SN - 1948-7185

VL - 12

SP - 3246

EP - 3252

JO - Journal of Physical Chemistry Letters

JF - Journal of Physical Chemistry Letters

IS - 12

ER -

X-ray Free Electron Laser-Induced Synthesis of ϵ-Iron Nitride at High Pressures

Abstract

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