Vapor-liquid equilibria of 2-butanol + aromatic hydrocarbons at 308.15 K

Sanjeev Maken; Umesh Bhardwaj; Bal Raj Deshwal; Krishan Chander Singh; Jin Won Park; Sang Do Han

doi:10.1080/00319100410001697882

Vapor-liquid equilibria of 2-butanol + aromatic hydrocarbons at 308.15 K

Sanjeev Maken, Umesh Bhardwaj, Bal Raj Deshwal, Krishan Chander Singh, Jin Won Park, Sang Do Han

Department of Chemical and Biomolecular Engineering

Research output: Contribution to journal › Article › peer-review

Abstract

Vapor-liquid equilibria (VLE) data of 2-butanol + benzene or toluene or o- or m- or p-xylene measured by static method at 308.15 ± 0.01 K over the entire composition range are reported. The excess molar Gibbs free energies of mixing (G^F) for these binary systems have been calculated from total vapor pressure data using Barker's method. The G^E for these binary systems are also analyzed in terms of the Mecke Kempter type of association model with a Flory contribution term using two interaction parameters and it has been found that this model describes well the G^E values of binary systems benzene or toluene.

Original language	English
Pages (from-to)	447-456
Number of pages	10
Journal	Physics and Chemistry of Liquids
Volume	42
Issue number	5
DOIs	https://doi.org/10.1080/00319100410001697882
Publication status	Published - 2004 Oct

Bibliographical note

Funding Information:
Sanjeev Maken thanks the Korean Federation of Science and Technology for the award of a fellowship under Brian Pool and Mr. Dharam Vir (IAS), Principal Secretary, Technical Education, Government of Haryana, and for the award of study leave from C.R. State College of Engineering, Haryana, India.

All Science Journal Classification (ASJC) codes

Electronic, Optical and Magnetic Materials
Condensed Matter Physics
Physical and Theoretical Chemistry
Materials Chemistry

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10.1080/00319100410001697882

Cite this

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title = "Vapor-liquid equilibria of 2-butanol + aromatic hydrocarbons at 308.15 K",

abstract = "Vapor-liquid equilibria (VLE) data of 2-butanol + benzene or toluene or o- or m- or p-xylene measured by static method at 308.15 ± 0.01 K over the entire composition range are reported. The excess molar Gibbs free energies of mixing (GF) for these binary systems have been calculated from total vapor pressure data using Barker's method. The GE for these binary systems are also analyzed in terms of the Mecke Kempter type of association model with a Flory contribution term using two interaction parameters and it has been found that this model describes well the GE values of binary systems benzene or toluene.",

author = "Sanjeev Maken and Umesh Bhardwaj and Deshwal, {Bal Raj} and Singh, {Krishan Chander} and Park, {Jin Won} and Han, {Sang Do}",

note = "Funding Information: Sanjeev Maken thanks the Korean Federation of Science and Technology for the award of a fellowship under Brian Pool and Mr. Dharam Vir (IAS), Principal Secretary, Technical Education, Government of Haryana, and for the award of study leave from C.R. State College of Engineering, Haryana, India.",

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AU - Singh, Krishan Chander

AU - Park, Jin Won

AU - Han, Sang Do

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AB - Vapor-liquid equilibria (VLE) data of 2-butanol + benzene or toluene or o- or m- or p-xylene measured by static method at 308.15 ± 0.01 K over the entire composition range are reported. The excess molar Gibbs free energies of mixing (GF) for these binary systems have been calculated from total vapor pressure data using Barker's method. The GE for these binary systems are also analyzed in terms of the Mecke Kempter type of association model with a Flory contribution term using two interaction parameters and it has been found that this model describes well the GE values of binary systems benzene or toluene.

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Vapor-liquid equilibria of 2-butanol + aromatic hydrocarbons at 308.15 K

Abstract

Bibliographical note

All Science Journal Classification (ASJC) codes

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