Unassisted water splitting from bipolar Pt/dye-sensitized TiO 2 photoelectrode arrays

Jong Hyeok Park, Allen J. Bard

Research output: Contribution to journalReview articlepeer-review

37 Citations (Scopus)


Direct photodecomposition of water to yield hydrogen and oxygen was achieved with bipolar Pt/dye-sensitized TiO 2 photoelectrode panels, capable of vectorial electron transfer. This novel photoelectrochemical cell, which can overcome the problems of the location of the semiconductor bandedges relative to the water decomposition energy level and the requirement of dye and semiconductor stability during water decomposition in aqueous solution, splits water directly upon illumination without any additional energy input. The maximum hydrogen evolution efficiency of this system, based on the short-circuit current, was 3.7%.

Original languageEnglish
Pages (from-to)G371-G375
JournalElectrochemical and Solid-State Letters
Issue number12
Publication statusPublished - 2005

All Science Journal Classification (ASJC) codes

  • Chemical Engineering(all)
  • Materials Science(all)
  • Physical and Theoretical Chemistry
  • Electrochemistry
  • Electrical and Electronic Engineering


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