Two-Step Pressure-Induced Superhydration in Small Pore Natrolite with Divalent Extra-Framework Cations

Donghoon Seoung; Yongmoon Lee; Chi Chang Kao; Thomas Vogt; Yongjae Lee

doi:10.1021/acs.chemmater.5b00506

Two-Step Pressure-Induced Superhydration in Small Pore Natrolite with Divalent Extra-Framework Cations

Donghoon Seoung, Yongmoon Lee, Chi Chang Kao, Thomas Vogt, Yongjae Lee

Institute of Earth·Atmosphere·Astronomy(BK21+)

Research output: Contribution to journal › Article › peer-review

18 Citations (Scopus)

Abstract

In situ high pressure X-ray powder diffraction studies of natrolite (NAT) containing the divalent extra-framework cations (EFC) Sr²⁺, Ca²⁺, Pb²⁺, and Cd²⁺ reveal that they can be superhydrated in the presence of water. In the case of Ca-NAT, Sr-NAT, and Pb-NAT pressure-induced hydration (PIH) inserts 40 H₂O/unit cell into the zeolite compared to 32 in superhydrated natrolites containing monovalent EFC. Cd-NAT is superhydrated in one step to a zeolite containing 32 H₂O/unit cell. PIH of Ca-NAT and Sr-NAT occurs in two steps. During PIH of Pb-NAT three distinct steps have been observed. The excess H₂O in natrolites with divalent EFC are accommodated on sites no longer required for charge compensation. Two distinct families with ordered and disordered EFC-water topologies have been found. Our work established the importance of both size and charge of the EFC in PIH.

Original language	English
Pages (from-to)	3874-3880
Number of pages	7
Journal	Chemistry of Materials
Volume	27
Issue number	11
DOIs	https://doi.org/10.1021/acs.chemmater.5b00506
Publication status	Published - 2015 Jun 9

Bibliographical note

Publisher Copyright:
© 2015 American Chemical Society.

All Science Journal Classification (ASJC) codes

Chemistry(all)
Chemical Engineering(all)
Materials Chemistry

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10.1021/acs.chemmater.5b00506

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title = "Two-Step Pressure-Induced Superhydration in Small Pore Natrolite with Divalent Extra-Framework Cations",

abstract = "In situ high pressure X-ray powder diffraction studies of natrolite (NAT) containing the divalent extra-framework cations (EFC) Sr2+, Ca2+, Pb2+, and Cd2+ reveal that they can be superhydrated in the presence of water. In the case of Ca-NAT, Sr-NAT, and Pb-NAT pressure-induced hydration (PIH) inserts 40 H2O/unit cell into the zeolite compared to 32 in superhydrated natrolites containing monovalent EFC. Cd-NAT is superhydrated in one step to a zeolite containing 32 H2O/unit cell. PIH of Ca-NAT and Sr-NAT occurs in two steps. During PIH of Pb-NAT three distinct steps have been observed. The excess H2O in natrolites with divalent EFC are accommodated on sites no longer required for charge compensation. Two distinct families with ordered and disordered EFC-water topologies have been found. Our work established the importance of both size and charge of the EFC in PIH.",

author = "Donghoon Seoung and Yongmoon Lee and Kao, {Chi Chang} and Thomas Vogt and Yongjae Lee",

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AU - Seoung, Donghoon

AU - Lee, Yongmoon

AU - Kao, Chi Chang

AU - Vogt, Thomas

AU - Lee, Yongjae

PY - 2015/6/9

Y1 - 2015/6/9

N2 - In situ high pressure X-ray powder diffraction studies of natrolite (NAT) containing the divalent extra-framework cations (EFC) Sr2+, Ca2+, Pb2+, and Cd2+ reveal that they can be superhydrated in the presence of water. In the case of Ca-NAT, Sr-NAT, and Pb-NAT pressure-induced hydration (PIH) inserts 40 H2O/unit cell into the zeolite compared to 32 in superhydrated natrolites containing monovalent EFC. Cd-NAT is superhydrated in one step to a zeolite containing 32 H2O/unit cell. PIH of Ca-NAT and Sr-NAT occurs in two steps. During PIH of Pb-NAT three distinct steps have been observed. The excess H2O in natrolites with divalent EFC are accommodated on sites no longer required for charge compensation. Two distinct families with ordered and disordered EFC-water topologies have been found. Our work established the importance of both size and charge of the EFC in PIH.

AB - In situ high pressure X-ray powder diffraction studies of natrolite (NAT) containing the divalent extra-framework cations (EFC) Sr2+, Ca2+, Pb2+, and Cd2+ reveal that they can be superhydrated in the presence of water. In the case of Ca-NAT, Sr-NAT, and Pb-NAT pressure-induced hydration (PIH) inserts 40 H2O/unit cell into the zeolite compared to 32 in superhydrated natrolites containing monovalent EFC. Cd-NAT is superhydrated in one step to a zeolite containing 32 H2O/unit cell. PIH of Ca-NAT and Sr-NAT occurs in two steps. During PIH of Pb-NAT three distinct steps have been observed. The excess H2O in natrolites with divalent EFC are accommodated on sites no longer required for charge compensation. Two distinct families with ordered and disordered EFC-water topologies have been found. Our work established the importance of both size and charge of the EFC in PIH.

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Two-Step Pressure-Induced Superhydration in Small Pore Natrolite with Divalent Extra-Framework Cations

Abstract

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