TY - JOUR
T1 - Tribenzosubporphines
T2 - Synthesis and characterization
AU - Inokuma, Yasuhide
AU - Kwon, Jung Ho
AU - Ahn, Tae Kyu
AU - Yoo, Min Chul
AU - Kim, Dongho
AU - Osuka, Atsuhiro
PY - 2006/1/30
Y1 - 2006/1/30
N2 - (Figure Presented) Keeping it in the family: A one-pot condensation with a boric acid template leads to the synthesis of subporphineboron(III) complexes (see example; B green, O red, N blue, C turquoise, H white), ring-contracted congeners of porphyrins. Facile axial ligand exchange reactions provide alkoxy- and carboxy-coordinated subporphyrins, which have bowl-shaped structures with a bowl depth that depends on the axial group.
AB - (Figure Presented) Keeping it in the family: A one-pot condensation with a boric acid template leads to the synthesis of subporphineboron(III) complexes (see example; B green, O red, N blue, C turquoise, H white), ring-contracted congeners of porphyrins. Facile axial ligand exchange reactions provide alkoxy- and carboxy-coordinated subporphyrins, which have bowl-shaped structures with a bowl depth that depends on the axial group.
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U2 - 10.1002/anie.200503426
DO - 10.1002/anie.200503426
M3 - Article
C2 - 16381040
AN - SCOPUS:32044471662
SN - 1433-7851
VL - 45
SP - 961
EP - 964
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
IS - 6
ER -