Transition behavior and ionic conductivity of lithium perchlorate-doped polystyrene-b-poly(2-vinylpyridine)

Bokyung Kim, Hyungju Ahn, Jong Hak Kim, Du Yeol Ryu, Jehan Kim

Research output: Contribution to journalArticlepeer-review

15 Citations (Scopus)


We report the transition behavior and the ionic conductivity of ion-doped amorphous block copolymer, based on two compositionally different polystyrene-block-poly(2-vinylpyridine) copolymers (PS-b-P2VPs) that can self-assemble into nanostructures, where P2VP block is ionophilic to lithium perchlorate (LiClO4). The transition temperatures of LiClO4-doped PS-b-P2VP, like the order-to-disorder transition (TODT), were measured by small-angle X-ray scattering (SAXS) and depolarized light scattering (DPLS). The selective ionic coordination to the nitrogen units of P2VP block leads to the increase of the repulsive interactions between two block components from weak- to strong-segregation regime with increasing amount of LiClO4, which results subsequently in the increased TODT. However, for a compositionally asymmetric PS-b-P2VP under lamellar morphology, the ionic conductivity by the addition of LiClO4 was remarkably increased at higher temperatures, representing that the effective ionic coordination at the greater volume fraction of P2VP block component improves the ionic conductivity as the temperature approaches to a rubbery phase.

Original languageEnglish
Pages (from-to)3822-3827
Number of pages6
Issue number15
Publication statusPublished - 2009 Jul 17

Bibliographical note

Funding Information:
This work was supported by the Nuclear R&D Programs and APCPI ERC program (R11-2007-050-02001) funded by the Ministry of Education, Science & Technology (MEST), Korea.

All Science Journal Classification (ASJC) codes

  • Organic Chemistry
  • Polymers and Plastics
  • Materials Chemistry


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