Transient X-ray diffraction reveals global and major reaction pathways for the photolysis of iodoform in solution

Jae Hyuk Lee; Joonghan Kim; Marco Cammarata; Qingyu Kong; Kyung Hwan Kim; Jungkweon Choi; Tae Kyu Kim; Michael Wulff; Hyotcherl Ihee

doi:10.1002/anie.200704150

Transient X-ray diffraction reveals global and major reaction pathways for the photolysis of iodoform in solution

Jae Hyuk Lee, Joonghan Kim, Marco Cammarata, Qingyu Kong, Kyung Hwan Kim, Jungkweon Choi, Tae Kyu Kim, Michael Wulff, Hyotcherl Ihee

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

23 Citations (Scopus)

Abstract

(Figure Presented) The structural dynamics of the photodissociation of iodoform in methanol (see picture: H blue, C green, I violet) are revealed by means of time-resolved X-ray diffraction in solution (also called transient X-ray liquidography because of its analogy to crystallography). While spectroscopic studies suggest the existence of isoiodoform, no signals are observed for this intermediate species in time-resolved diffraction experiments performed using time delays between 100 ps and 3 μs.

Original language	English
Pages (from-to)	1047-1050
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	47
Issue number	6
DOIs	https://doi.org/10.1002/anie.200704150
Publication status	Published - 2008

All Science Journal Classification (ASJC) codes

Catalysis
Chemistry(all)

Access to Document

10.1002/anie.200704150

Cite this

@article{a9772fa4fc994717bc1e08151d184607,

title = "Transient X-ray diffraction reveals global and major reaction pathways for the photolysis of iodoform in solution",

abstract = "(Figure Presented) The structural dynamics of the photodissociation of iodoform in methanol (see picture: H blue, C green, I violet) are revealed by means of time-resolved X-ray diffraction in solution (also called transient X-ray liquidography because of its analogy to crystallography). While spectroscopic studies suggest the existence of isoiodoform, no signals are observed for this intermediate species in time-resolved diffraction experiments performed using time delays between 100 ps and 3 μs.",

author = "Lee, {Jae Hyuk} and Joonghan Kim and Marco Cammarata and Qingyu Kong and Kim, {Kyung Hwan} and Jungkweon Choi and Kim, {Tae Kyu} and Michael Wulff and Hyotcherl Ihee",

year = "2008",

doi = "10.1002/anie.200704150",

language = "English",

volume = "47",

pages = "1047--1050",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "John Wiley and Sons Ltd",

number = "6",

}

TY - JOUR

T1 - Transient X-ray diffraction reveals global and major reaction pathways for the photolysis of iodoform in solution

AU - Lee, Jae Hyuk

AU - Kim, Joonghan

AU - Cammarata, Marco

AU - Kong, Qingyu

AU - Kim, Kyung Hwan

AU - Choi, Jungkweon

AU - Kim, Tae Kyu

AU - Wulff, Michael

AU - Ihee, Hyotcherl

PY - 2008

Y1 - 2008

N2 - (Figure Presented) The structural dynamics of the photodissociation of iodoform in methanol (see picture: H blue, C green, I violet) are revealed by means of time-resolved X-ray diffraction in solution (also called transient X-ray liquidography because of its analogy to crystallography). While spectroscopic studies suggest the existence of isoiodoform, no signals are observed for this intermediate species in time-resolved diffraction experiments performed using time delays between 100 ps and 3 μs.

AB - (Figure Presented) The structural dynamics of the photodissociation of iodoform in methanol (see picture: H blue, C green, I violet) are revealed by means of time-resolved X-ray diffraction in solution (also called transient X-ray liquidography because of its analogy to crystallography). While spectroscopic studies suggest the existence of isoiodoform, no signals are observed for this intermediate species in time-resolved diffraction experiments performed using time delays between 100 ps and 3 μs.

UR - http://www.scopus.com/inward/record.url?scp=38849137272&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=38849137272&partnerID=8YFLogxK

U2 - 10.1002/anie.200704150

DO - 10.1002/anie.200704150

M3 - Article

C2 - 18165964

AN - SCOPUS:38849137272

SN - 1433-7851

VL - 47

SP - 1047

EP - 1050

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 6

ER -

Transient X-ray diffraction reveals global and major reaction pathways for the photolysis of iodoform in solution

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this