Toward the rational design of supramolecular coordination polymers. The effect of solvent and substituent changes on the structure of self-assembled metal-organometallic networks

Moonhyun Oh; Gene B. Carpenter; D. A. Sweigart

doi:10.1021/om0302600

Toward the rational design of supramolecular coordination polymers. The effect of solvent and substituent changes on the structure of self-assembled metal-organometallic networks

Moonhyun Oh, Gene B. Carpenter, D. A. Sweigart

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

49 Citations (Scopus)

Abstract

Self-assembly of the π-complex (η⁴-benzoquinone)Mn(CO)₃^- (QMTC) with metal ions [Mn(II), Co(II), Zn(II)] generates neutral metal-organometallic coordination networks (MOMNs). The network architecture can be controlled by (1) a solvent-induced change in coordination geometry at the metal nodes and (2) the introduction of substituents on the benzoquinone ring.

Original language	English
Pages (from-to)	2364-2366
Number of pages	3
Journal	Organometallics
Volume	22
Issue number	12
DOIs	https://doi.org/10.1021/om0302600
Publication status	Published - 2003 Jun 9

All Science Journal Classification (ASJC) codes

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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10.1021/om0302600

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abstract = "Self-assembly of the π-complex (η4-benzoquinone)Mn(CO)3- (QMTC) with metal ions [Mn(II), Co(II), Zn(II)] generates neutral metal-organometallic coordination networks (MOMNs). The network architecture can be controlled by (1) a solvent-induced change in coordination geometry at the metal nodes and (2) the introduction of substituents on the benzoquinone ring.",

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Toward the rational design of supramolecular coordination polymers. The effect of solvent and substituent changes on the structure of self-assembled metal-organometallic networks

Abstract

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