Total synthesis of hamigerans: Part 2. Implementation of the intramolecular Diels - Alder trapping of photochemically generated hydroxy-o-quinodimethanes; strategy and completion of the synthesis

K. C. Nicolaou, David Gray, Jinsung Tae

Research output: Contribution to journalArticlepeer-review

94 Citations (Scopus)

Abstract

The synthesis of libraries of natural products is important for chemical biology studies. With this in mind, the intramolecular Diels - Alder reaction of photo-chemically generated hydroxy-o-quinodimethanes was used to produce the naturally occurring hamigerans 1-4 and several of their epimers.

Original languageEnglish
Pages (from-to)3679-3683
Number of pages5
JournalAngewandte Chemie - International Edition
Volume40
Issue number19
DOIs
Publication statusPublished - 2001 Oct 1

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

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