Thiofluorographene-hydrophilic graphene derivative with semiconducting and genosensing properties

Veronika Urbanová; Kateřina Holá; Athanasios B. Bourlinos; Klára Čépe; Adriano Ambrosi; Adeline Huiling Loo; Martin Pumera; František Karlický; Michal Otyepka; Radek Zbořil

doi:10.1002/adma.201500094

Thiofluorographene-hydrophilic graphene derivative with semiconducting and genosensing properties

Veronika Urbanová, Kateřina Holá, Athanasios B. Bourlinos, Klára Čépe, Adriano Ambrosi, Adeline Huiling Loo, Martin Pumera, František Karlický, Michal Otyepka, Radek Zbořil

Department of Chemical and Biomolecular Engineering

Research output: Contribution to journal › Article › peer-review

85 Citations (Scopus)

Abstract

We present the first example of covalent chemistry on fluorographene, enabling the attachment of -SH groups through nucleophilic substitution of fluorine in a polar solvent. The resulting thiographene-like, 2D derivative is hydrophilic with semiconducting properties and bandgap between 1 and 2 eV depending on F/SH ratio. Thiofluorographene is applied in DNA biosensing by electrochemical impedance spectroscopy.

Original language	English
Pages (from-to)	2305-2310
Number of pages	6
Journal	Advanced Materials
Volume	27
Issue number	14
DOIs	https://doi.org/10.1002/adma.201500094
Publication status	Published - 2015 Apr 8

Bibliographical note

Publisher Copyright:
© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

All Science Journal Classification (ASJC) codes

Materials Science(all)
Mechanics of Materials
Mechanical Engineering

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10.1002/adma.201500094

Cite this

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abstract = "We present the first example of covalent chemistry on fluorographene, enabling the attachment of -SH groups through nucleophilic substitution of fluorine in a polar solvent. The resulting thiographene-like, 2D derivative is hydrophilic with semiconducting properties and bandgap between 1 and 2 eV depending on F/SH ratio. Thiofluorographene is applied in DNA biosensing by electrochemical impedance spectroscopy.",

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note = "Publisher Copyright: {\textcopyright} 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.",

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doi = "10.1002/adma.201500094",

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T1 - Thiofluorographene-hydrophilic graphene derivative with semiconducting and genosensing properties

AU - Urbanová, Veronika

AU - Holá, Kateřina

AU - Bourlinos, Athanasios B.

AU - Čépe, Klára

AU - Ambrosi, Adriano

AU - Loo, Adeline Huiling

AU - Pumera, Martin

AU - Karlický, František

AU - Otyepka, Michal

AU - Zbořil, Radek

PY - 2015/4/8

Y1 - 2015/4/8

N2 - We present the first example of covalent chemistry on fluorographene, enabling the attachment of -SH groups through nucleophilic substitution of fluorine in a polar solvent. The resulting thiographene-like, 2D derivative is hydrophilic with semiconducting properties and bandgap between 1 and 2 eV depending on F/SH ratio. Thiofluorographene is applied in DNA biosensing by electrochemical impedance spectroscopy.

AB - We present the first example of covalent chemistry on fluorographene, enabling the attachment of -SH groups through nucleophilic substitution of fluorine in a polar solvent. The resulting thiographene-like, 2D derivative is hydrophilic with semiconducting properties and bandgap between 1 and 2 eV depending on F/SH ratio. Thiofluorographene is applied in DNA biosensing by electrochemical impedance spectroscopy.

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JO - Advanced Materials

JF - Advanced Materials

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ER -

Thiofluorographene-hydrophilic graphene derivative with semiconducting and genosensing properties

Abstract

Bibliographical note

All Science Journal Classification (ASJC) codes

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