Thermoelectric and mechanical properties of Zn 4Sb 3 polycrystals sintered by spark plasma sintering

Min Seok Song, Soon Mok Choi, Won Seon Seo, Jooho Moon, Kyung Wook Jang

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12 Citations (Scopus)


β-Zn 4Sb 3 has attracted much interest as a thermoelectric material because of its potential for power-generation applications in a moderate temperature range (450 ~ 650 K). In general, three kinds of considerations have been reported for the fabrication of a polycrystalline β-Zn 4Sb 3 bulk sample: (i) a problem in chemical stability, (ii) cracks in bulk specimens owing to a phase transition of the Zn 4Sb 3 composition resulting in stress during cooling, and (iii) the requirement for high bulk density. In this study, a pure Zn 4Sb 3 phase with a high define ZT(figure of merit) value was synthesized by using a vacuum melting process and a vacuum annealing process, followed by a spark plasma sintering (SPS) method. Fabricating a single-phase specimen with high bulk density by means of optimizing the SPS conditions (temperature and pressure) was significant for obtaining high performance in the Zn 4Sb 3 thermoelectric system. The maximum ZT value (0.98) was attained at a 573 K measurement temperature for the specimen sintered with the optimized SPS conditions (723 K, 40 MPa).

Original languageEnglish
Pages (from-to)1735-1740
Number of pages6
JournalJournal of the Korean Physical Society
Issue number10
Publication statusPublished - 2012 May

Bibliographical note

Funding Information:
This work was supported by a Fundamental R & D Program for Core Technology of Materials (K0006007) grant funded by the Ministry of Knowledge Economy, Republic of Korea.

All Science Journal Classification (ASJC) codes

  • Physics and Astronomy(all)


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