Thermal stability of amorphous oxide in Al87Ni3Y10 metallic glass

Kang Cheol Kim; Ka Ram Lim; Eun Sung Lee; Won Tae Kim; Annett Gebert; Jürgen Eckert; Do Hyang Kim

doi:10.1016/j.corsci.2013.08.010

Thermal stability of amorphous oxide in Al₈₇Ni₃Y₁₀ metallic glass

Kang Cheol Kim, Ka Ram Lim, Eun Sung Lee, Won Tae Kim, Annett Gebert, Jürgen Eckert, Do Hyang Kim

Department of Materials Science and Engineering

Research output: Contribution to journal › Short survey › peer-review

15 Citations (Scopus)

Abstract

The oxidation behavior of melt-spun Al₈₇Ni₃Y₁₀ metallic glass at 873K is investigated in the present study. The simultaneous presence of aluminum and yttrium in the oxide markedly promotes the thermal stability of the amorphous oxide phase, enabling the growth of the amorphous oxide layer up to ~100nm thickness. The stability of the amorphous oxide can be enhanced by suppressing the nucleation of the crystalline oxide at the oxide/matrix interface. The dense structure of aluminum-yttrium oxide due to large difference in ionic radius between aluminum and yttrium ions disturbs the diffusion of oxygen ions through the amorphous oxide layer.

Original language	English
Pages (from-to)	1-5
Number of pages	5
Journal	Corrosion Science
Volume	77
DOIs	https://doi.org/10.1016/j.corsci.2013.08.010
Publication status	Published - 2013 Dec

Bibliographical note

Funding Information:
This work was supported by the Global Research Laboratory Program of the Korean Ministry of Education, Science and Technology.

All Science Journal Classification (ASJC) codes

Chemistry(all)
Chemical Engineering(all)
Materials Science(all)

Access to Document

10.1016/j.corsci.2013.08.010

Cite this

@article{3326e2f3cca34ab490bacbd84b69413c,

title = "Thermal stability of amorphous oxide in Al87Ni3Y10 metallic glass",

abstract = "The oxidation behavior of melt-spun Al87Ni3Y10 metallic glass at 873K is investigated in the present study. The simultaneous presence of aluminum and yttrium in the oxide markedly promotes the thermal stability of the amorphous oxide phase, enabling the growth of the amorphous oxide layer up to ~100nm thickness. The stability of the amorphous oxide can be enhanced by suppressing the nucleation of the crystalline oxide at the oxide/matrix interface. The dense structure of aluminum-yttrium oxide due to large difference in ionic radius between aluminum and yttrium ions disturbs the diffusion of oxygen ions through the amorphous oxide layer.",

author = "Kim, {Kang Cheol} and Lim, {Ka Ram} and Lee, {Eun Sung} and Kim, {Won Tae} and Annett Gebert and J{\"u}rgen Eckert and Kim, {Do Hyang}",

note = "Funding Information: This work was supported by the Global Research Laboratory Program of the Korean Ministry of Education, Science and Technology.",

year = "2013",

month = dec,

doi = "10.1016/j.corsci.2013.08.010",

language = "English",

volume = "77",

pages = "1--5",

journal = "Corrosion Science",

issn = "0010-938X",

publisher = "Elsevier Limited",

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TY - JOUR

T1 - Thermal stability of amorphous oxide in Al87Ni3Y10 metallic glass

AU - Kim, Kang Cheol

AU - Lim, Ka Ram

AU - Lee, Eun Sung

AU - Kim, Won Tae

AU - Gebert, Annett

AU - Eckert, Jürgen

AU - Kim, Do Hyang

N1 - Funding Information: This work was supported by the Global Research Laboratory Program of the Korean Ministry of Education, Science and Technology.

PY - 2013/12

Y1 - 2013/12

N2 - The oxidation behavior of melt-spun Al87Ni3Y10 metallic glass at 873K is investigated in the present study. The simultaneous presence of aluminum and yttrium in the oxide markedly promotes the thermal stability of the amorphous oxide phase, enabling the growth of the amorphous oxide layer up to ~100nm thickness. The stability of the amorphous oxide can be enhanced by suppressing the nucleation of the crystalline oxide at the oxide/matrix interface. The dense structure of aluminum-yttrium oxide due to large difference in ionic radius between aluminum and yttrium ions disturbs the diffusion of oxygen ions through the amorphous oxide layer.

AB - The oxidation behavior of melt-spun Al87Ni3Y10 metallic glass at 873K is investigated in the present study. The simultaneous presence of aluminum and yttrium in the oxide markedly promotes the thermal stability of the amorphous oxide phase, enabling the growth of the amorphous oxide layer up to ~100nm thickness. The stability of the amorphous oxide can be enhanced by suppressing the nucleation of the crystalline oxide at the oxide/matrix interface. The dense structure of aluminum-yttrium oxide due to large difference in ionic radius between aluminum and yttrium ions disturbs the diffusion of oxygen ions through the amorphous oxide layer.

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U2 - 10.1016/j.corsci.2013.08.010

DO - 10.1016/j.corsci.2013.08.010

M3 - Short survey

AN - SCOPUS:84885178158

SN - 0010-938X

VL - 77

SP - 1

EP - 5

JO - Corrosion Science

JF - Corrosion Science

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