The polyoxo-22-palladate(II), [Na2Pd II 22 O12(AsVO4)15(AsVO3OH)]25-

Natalya V. Izarova; Zhengguo Lin; Peng Yang; Aleksandar Kondinski; Nina Vankova; Thomas Heine; Ulrich Kortz

doi:10.1039/c5dt04526f

The polyoxo-22-palladate(II), [Na₂Pd II 22 O₁₂(As^VO₄)₁₅(As^VO₃OH)]^25-

Natalya V. Izarova, Zhengguo Lin, Peng Yang, Aleksandar Kondinski, Nina Vankova, Thomas Heine, Ulrich Kortz

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

14 Citations (Scopus)

Abstract

The polyoxo-22-palladate [Na₂PdII22O₁₂(As^VO₄)₁₅(As^VO₃OH)]^25- (1), which represents a novel polyoxo-noble-metalate structural type, was synthesized by reaction of Pd²⁺ and AsO₄^3- ions in aqueous solution. Polyanion 1 comprises two {NaPd₁₁} units linked by two arsenate bridges, and hence represents the first example of a defect, monolacunary {Pd₁₁} polyoxopalladate nanocube with arsenate capping groups. The title polyanion was characterized in the solid state as well as by theoretical calculations.

Original language	English
Pages (from-to)	2394-2398
Number of pages	5
Journal	Dalton Transactions
Volume	45
Issue number	6
DOIs	https://doi.org/10.1039/c5dt04526f
Publication status	Published - 2016

Bibliographical note

Funding Information:
This work was supported by the German Science Foundation (DFG KO-2288/20-1, DFG-KO-2288/16-1, DFG-IZ-60/1-1) and Jacobs University. U. K. acknowledges the EU-COST Action CM1203 (PoCheMoN) and Johnson Matthey PLC for a loan of palladium(II) salts. P. Y. acknowledges the China Scholarship Council (CSC) for a doctoral fellowship. We thank Yixian Xiang for help with some experimental work. The computational part was performed by using the resources of CLAMV (Computational Laboratory for Analysis, Modeling and Visualization) at Jacobs University.

Publisher Copyright:
© The Royal Society of Chemistry 2016.

All Science Journal Classification (ASJC) codes

Inorganic Chemistry

Access to Document

10.1039/c5dt04526f

Cite this

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title = "The polyoxo-22-palladate(II), [Na2Pd II 22 O12(AsVO4)15(AsVO3OH)]25-",

abstract = "The polyoxo-22-palladate [Na2PdII22O12(AsVO4)15(AsVO3OH)]25- (1), which represents a novel polyoxo-noble-metalate structural type, was synthesized by reaction of Pd2+ and AsO43- ions in aqueous solution. Polyanion 1 comprises two {NaPd11} units linked by two arsenate bridges, and hence represents the first example of a defect, monolacunary {Pd11} polyoxopalladate nanocube with arsenate capping groups. The title polyanion was characterized in the solid state as well as by theoretical calculations.",

author = "Izarova, {Natalya V.} and Zhengguo Lin and Peng Yang and Aleksandar Kondinski and Nina Vankova and Thomas Heine and Ulrich Kortz",

note = "Funding Information: This work was supported by the German Science Foundation (DFG KO-2288/20-1, DFG-KO-2288/16-1, DFG-IZ-60/1-1) and Jacobs University. U. K. acknowledges the EU-COST Action CM1203 (PoCheMoN) and Johnson Matthey PLC for a loan of palladium(II) salts. P. Y. acknowledges the China Scholarship Council (CSC) for a doctoral fellowship. We thank Yixian Xiang for help with some experimental work. The computational part was performed by using the resources of CLAMV (Computational Laboratory for Analysis, Modeling and Visualization) at Jacobs University. Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2016.",

year = "2016",

doi = "10.1039/c5dt04526f",

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AU - Izarova, Natalya V.

AU - Lin, Zhengguo

AU - Yang, Peng

AU - Kondinski, Aleksandar

AU - Vankova, Nina

AU - Heine, Thomas

AU - Kortz, Ulrich

N1 - Funding Information: This work was supported by the German Science Foundation (DFG KO-2288/20-1, DFG-KO-2288/16-1, DFG-IZ-60/1-1) and Jacobs University. U. K. acknowledges the EU-COST Action CM1203 (PoCheMoN) and Johnson Matthey PLC for a loan of palladium(II) salts. P. Y. acknowledges the China Scholarship Council (CSC) for a doctoral fellowship. We thank Yixian Xiang for help with some experimental work. The computational part was performed by using the resources of CLAMV (Computational Laboratory for Analysis, Modeling and Visualization) at Jacobs University. Publisher Copyright: © The Royal Society of Chemistry 2016.

PY - 2016

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