The polyoxo-22-palladate(II), [Na2Pd II 22 O12(AsVO4)15(AsVO3OH)]25-

Natalya V. Izarova, Zhengguo Lin, Peng Yang, Aleksandar Kondinski, Nina Vankova, Thomas Heine, Ulrich Kortz

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14 Citations (Scopus)


The polyoxo-22-palladate [Na2PdII22O12(AsVO4)15(AsVO3OH)]25- (1), which represents a novel polyoxo-noble-metalate structural type, was synthesized by reaction of Pd2+ and AsO43- ions in aqueous solution. Polyanion 1 comprises two {NaPd11} units linked by two arsenate bridges, and hence represents the first example of a defect, monolacunary {Pd11} polyoxopalladate nanocube with arsenate capping groups. The title polyanion was characterized in the solid state as well as by theoretical calculations.

Original languageEnglish
Pages (from-to)2394-2398
Number of pages5
JournalDalton Transactions
Issue number6
Publication statusPublished - 2016

Bibliographical note

Funding Information:
This work was supported by the German Science Foundation (DFG KO-2288/20-1, DFG-KO-2288/16-1, DFG-IZ-60/1-1) and Jacobs University. U. K. acknowledges the EU-COST Action CM1203 (PoCheMoN) and Johnson Matthey PLC for a loan of palladium(II) salts. P. Y. acknowledges the China Scholarship Council (CSC) for a doctoral fellowship. We thank Yixian Xiang for help with some experimental work. The computational part was performed by using the resources of CLAMV (Computational Laboratory for Analysis, Modeling and Visualization) at Jacobs University.

Publisher Copyright:
© The Royal Society of Chemistry 2016.

All Science Journal Classification (ASJC) codes

  • Inorganic Chemistry


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