The effect of crosslinked networks with poly(ethylene glycol) on sulfonated polyimide for polymer electrolyte membrane fuel cell

Seung Jin Yang; Wonbong Jang; Choonkeun Lee; Yong Gun Shul; Haksoo Han

doi:10.1002/polb.20448

The effect of crosslinked networks with poly(ethylene glycol) on sulfonated polyimide for polymer electrolyte membrane fuel cell

Seung Jin Yang, Wonbong Jang, Choonkeun Lee, Yong Gun Shul, Haksoo Han

Department of Chemical and Biomolecular Engineering

Research output: Contribution to journal › Article › peer-review

55 Citations (Scopus)

Abstract

The effect of crosslinking by a hydrophilic group on a sulfonated polyimide electrolyte membrane fuel cell, was investigated. The sulfonated polyimides end-capped with maleic anhydride were self-crosslinked with poly(ethylene glycol) diacrylate. It was observed that thermal stability was good for all the sulfonated polyimides that exhibited a three-step degradation pattern. The results show that the proton conductivity of the crosslinked sulfonated polyimides with poly(ethylene glycol) diacrylate increased with the increase in poly(ethylene glycol) diacrylate despite the fact that the ion exchange capacity was decreased.

Original language	English
Pages (from-to)	1455-1464
Number of pages	10
Journal	Journal of Polymer Science, Part B: Polymer Physics
Volume	43
Issue number	12
DOIs	https://doi.org/10.1002/polb.20448
Publication status	Published - 2005 Jun 15

All Science Journal Classification (ASJC) codes

Condensed Matter Physics
Physical and Theoretical Chemistry
Polymers and Plastics
Materials Chemistry

Access to Document

10.1002/polb.20448

Cite this

@article{f0a953ee3a9241cbb5125342e11c2654,

title = "The effect of crosslinked networks with poly(ethylene glycol) on sulfonated polyimide for polymer electrolyte membrane fuel cell",

abstract = "The effect of crosslinking by a hydrophilic group on a sulfonated polyimide electrolyte membrane fuel cell, was investigated. The sulfonated polyimides end-capped with maleic anhydride were self-crosslinked with poly(ethylene glycol) diacrylate. It was observed that thermal stability was good for all the sulfonated polyimides that exhibited a three-step degradation pattern. The results show that the proton conductivity of the crosslinked sulfonated polyimides with poly(ethylene glycol) diacrylate increased with the increase in poly(ethylene glycol) diacrylate despite the fact that the ion exchange capacity was decreased.",

author = "Yang, {Seung Jin} and Wonbong Jang and Choonkeun Lee and Shul, {Yong Gun} and Haksoo Han",

year = "2005",

month = jun,

day = "15",

doi = "10.1002/polb.20448",

language = "English",

volume = "43",

pages = "1455--1464",

journal = "Journal of Polymer Science, Polymer Letters Edition",

issn = "0887-6266",

publisher = "John Wiley and Sons Inc.",

number = "12",

}

TY - JOUR

T1 - The effect of crosslinked networks with poly(ethylene glycol) on sulfonated polyimide for polymer electrolyte membrane fuel cell

AU - Yang, Seung Jin

AU - Jang, Wonbong

AU - Lee, Choonkeun

AU - Shul, Yong Gun

AU - Han, Haksoo

PY - 2005/6/15

Y1 - 2005/6/15

N2 - The effect of crosslinking by a hydrophilic group on a sulfonated polyimide electrolyte membrane fuel cell, was investigated. The sulfonated polyimides end-capped with maleic anhydride were self-crosslinked with poly(ethylene glycol) diacrylate. It was observed that thermal stability was good for all the sulfonated polyimides that exhibited a three-step degradation pattern. The results show that the proton conductivity of the crosslinked sulfonated polyimides with poly(ethylene glycol) diacrylate increased with the increase in poly(ethylene glycol) diacrylate despite the fact that the ion exchange capacity was decreased.

AB - The effect of crosslinking by a hydrophilic group on a sulfonated polyimide electrolyte membrane fuel cell, was investigated. The sulfonated polyimides end-capped with maleic anhydride were self-crosslinked with poly(ethylene glycol) diacrylate. It was observed that thermal stability was good for all the sulfonated polyimides that exhibited a three-step degradation pattern. The results show that the proton conductivity of the crosslinked sulfonated polyimides with poly(ethylene glycol) diacrylate increased with the increase in poly(ethylene glycol) diacrylate despite the fact that the ion exchange capacity was decreased.

UR - http://www.scopus.com/inward/record.url?scp=20844438225&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=20844438225&partnerID=8YFLogxK

U2 - 10.1002/polb.20448

DO - 10.1002/polb.20448

M3 - Article

AN - SCOPUS:20844438225

SN - 0887-6266

VL - 43

SP - 1455

EP - 1464

JO - Journal of Polymer Science, Polymer Letters Edition

JF - Journal of Polymer Science, Polymer Letters Edition

IS - 12

ER -

The effect of crosslinked networks with poly(ethylene glycol) on sulfonated polyimide for polymer electrolyte membrane fuel cell

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this