Textile-based high-performance hydrogen evolution of low-temperature atomic layer deposition of cobalt sulfide

Donghyun Kim, Jeong Gyu Song, Hyungmo Yang, Hoonkyung Lee, Jusang Park, Hyungjun Kim

Research output: Contribution to journalArticlepeer-review

16 Citations (Scopus)


Hydrogen is an appealing green energy resource to meet increasing energy demands. To produce hydrogen using the hydrogen evolution reaction (HER), platinum, an expensive and scarce metal, is commonly used and plays a crucial role in maximizing catalytic performance. Transition metal chalcogenides, especially cobalt sulfides (CoS x ), are considered an alternative to platinum because of their electrochemical properties, for example, low Tafel slopes and overpotentials. Here, we report a light weight, flexible textile-based HER catalyst through a low-temperature process using the atomic layer deposition (ALD) of CoS x . The electrochemical properties of HER catalysts were investigated and found to be impressive, with a low Tafel slope of 41 mV dec -1 and high exchange current density, demonstrating that these are one of the best characteristics among textile-based HER catalysts. The superb catalytic performances were attributed to the amorphous CoS x phase, confirmed by DFT calculations. This study demonstrates that the integration of HER catalysts with textiles allows the development of highly efficient hydrogen energy production systems.

Original languageEnglish
Pages (from-to)844-850
Number of pages7
Issue number3
Publication statusPublished - 2019 Jan 21

Bibliographical note

Publisher Copyright:
© 2019 The Royal Society of Chemistry.

All Science Journal Classification (ASJC) codes

  • Materials Science(all)


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