Tetrakis(4-tert-butylphenyl) substituted and fused quinoidal porphyrins

Wangdong Zeng; Byung Sun Lee; Young Mo Sung; Kuo Wei Huang; Yuan Li; Dongho Kim; Jishan Wu

doi:10.1039/c2cc33728b

Tetrakis(4-tert-butylphenyl) substituted and fused quinoidal porphyrins

Wangdong Zeng, Byung Sun Lee, Young Mo Sung, Kuo Wei Huang, Yuan Li, Dongho Kim, Jishan Wu

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

32 Citations (Scopus)

Abstract

4-tert-Butylphenyl-substituted and fused quinoidal porphyrins 1 and 2 are prepared for the first time. They show (1) intense one-photon absorption in the far-red/near-infrared region, (2) enhanced two-photon absorption compared with aromatic porphyrin monomers, and (3) amphoteric redox behavior. Their geometry and electronic structure are studied by DFT calculations.

Original language	English
Pages (from-to)	7684-7686
Number of pages	3
Journal	Chemical Communications
Volume	48
Issue number	62
DOIs	https://doi.org/10.1039/c2cc33728b
Publication status	Published - 2012 Jul 9

All Science Journal Classification (ASJC) codes

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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abstract = "4-tert-Butylphenyl-substituted and fused quinoidal porphyrins 1 and 2 are prepared for the first time. They show (1) intense one-photon absorption in the far-red/near-infrared region, (2) enhanced two-photon absorption compared with aromatic porphyrin monomers, and (3) amphoteric redox behavior. Their geometry and electronic structure are studied by DFT calculations.",

author = "Wangdong Zeng and {Sun Lee}, Byung and {Mo Sung}, Young and Huang, {Kuo Wei} and Yuan Li and Dongho Kim and Jishan Wu",

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AU - Zeng, Wangdong

AU - Sun Lee, Byung

AU - Mo Sung, Young

AU - Huang, Kuo Wei

AU - Li, Yuan

AU - Kim, Dongho

AU - Wu, Jishan

PY - 2012/7/9

Y1 - 2012/7/9

N2 - 4-tert-Butylphenyl-substituted and fused quinoidal porphyrins 1 and 2 are prepared for the first time. They show (1) intense one-photon absorption in the far-red/near-infrared region, (2) enhanced two-photon absorption compared with aromatic porphyrin monomers, and (3) amphoteric redox behavior. Their geometry and electronic structure are studied by DFT calculations.

AB - 4-tert-Butylphenyl-substituted and fused quinoidal porphyrins 1 and 2 are prepared for the first time. They show (1) intense one-photon absorption in the far-red/near-infrared region, (2) enhanced two-photon absorption compared with aromatic porphyrin monomers, and (3) amphoteric redox behavior. Their geometry and electronic structure are studied by DFT calculations.

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Tetrakis(4-tert-butylphenyl) substituted and fused quinoidal porphyrins

Abstract

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