Synthesis, properties, and gas separation studies of a robust diimide-based microporous organic polymer

Omar K. Farha; Alexander M. Spokoyny; Brad G. Hauser; Youn Sang Bae; Samantha E. Brown; Randall Q. Snurr; Chad A. Mirkin; Joseph T. Hupp

doi:10.1021/cm901280w

Synthesis, properties, and gas separation studies of a robust diimide-based microporous organic polymer

Omar K. Farha, Alexander M. Spokoyny, Brad G. Hauser, Youn Sang Bae, Samantha E. Brown, Randall Q. Snurr, Chad A. Mirkin, Joseph T. Hupp

Department of Chemical and Biomolecular Engineering

Research output: Contribution to journal › Article › peer-review

260 Citations (Scopus)

Abstract

The synthesis of a new porous organic polymer that features high surface area and pores of appropriate size and composition to capture CO ₂ from mixtures with methane, was reported. The desired micro-and ultramicro-porosity was engendered by using a tetrahedral building block that is expected to produce a three-dimensional network. Single component adsorption isotherms for CO ₂ and CH ₄ were measured volumetrically for diimide subunits heated under a vacuum at 160°C. The selectivities for CO ₂ CH ₄ mixtures were calculated using ideal adsorbed solution theory (IAST). The first of these new materials, simply made from inexpensive precursors, shows outstanding thermal and chemical stability, and exceptional promise for CO ₂ CH ₄ separation.

Original language	English
Pages (from-to)	3033-3035
Number of pages	3
Journal	Chemistry of Materials
Volume	21
Issue number	14
DOIs	https://doi.org/10.1021/cm901280w
Publication status	Published - 2009 Jul 28

All Science Journal Classification (ASJC) codes

Chemistry(all)
Chemical Engineering(all)
Materials Chemistry

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10.1021/cm901280w

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abstract = "The synthesis of a new porous organic polymer that features high surface area and pores of appropriate size and composition to capture CO 2 from mixtures with methane, was reported. The desired micro-and ultramicro-porosity was engendered by using a tetrahedral building block that is expected to produce a three-dimensional network. Single component adsorption isotherms for CO 2 and CH 4 were measured volumetrically for diimide subunits heated under a vacuum at 160°C. The selectivities for CO 2 CH 4 mixtures were calculated using ideal adsorbed solution theory (IAST). The first of these new materials, simply made from inexpensive precursors, shows outstanding thermal and chemical stability, and exceptional promise for CO 2 CH 4 separation.",

author = "Farha, {Omar K.} and Spokoyny, {Alexander M.} and Hauser, {Brad G.} and Bae, {Youn Sang} and Brown, {Samantha E.} and Snurr, {Randall Q.} and Mirkin, {Chad A.} and Hupp, {Joseph T.}",

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AU - Farha, Omar K.

AU - Spokoyny, Alexander M.

AU - Hauser, Brad G.

AU - Bae, Youn Sang

AU - Brown, Samantha E.

AU - Snurr, Randall Q.

AU - Mirkin, Chad A.

AU - Hupp, Joseph T.

PY - 2009/7/28

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AB - The synthesis of a new porous organic polymer that features high surface area and pores of appropriate size and composition to capture CO 2 from mixtures with methane, was reported. The desired micro-and ultramicro-porosity was engendered by using a tetrahedral building block that is expected to produce a three-dimensional network. Single component adsorption isotherms for CO 2 and CH 4 were measured volumetrically for diimide subunits heated under a vacuum at 160°C. The selectivities for CO 2 CH 4 mixtures were calculated using ideal adsorbed solution theory (IAST). The first of these new materials, simply made from inexpensive precursors, shows outstanding thermal and chemical stability, and exceptional promise for CO 2 CH 4 separation.

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Synthesis, properties, and gas separation studies of a robust diimide-based microporous organic polymer

Abstract

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