Synthesis of solution-stable PEDOT-coated sulfonated polystyrene copolymer PEDOT:P(SS-co-St) particles for all-organic NIR-shielding films

Soeun Im; Chanil Park; Wonseok Cho; Jooyoung Kim; Minseok Jeong; Jung Hyun Kim

doi:10.3390/coatings9030151

Synthesis of solution-stable PEDOT-coated sulfonated polystyrene copolymer PEDOT:P(SS-co-St) particles for all-organic NIR-shielding films

Soeun Im, Chanil Park, Wonseok Cho, Jooyoung Kim, Minseok Jeong, Jung Hyun Kim

Department of Chemical and Biomolecular Engineering

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

We prepared poly(3,4-ethylenedioxythiophene) (PEDOT)-coated sulfonated polystyrene copolymer particles as efficient heat-shielding agents, which showed strong near-infrared (NIR) absorption, with high solid contents and good solution stability. The poly(styrene sulfonate-co-styrene) (P(SS-co-St)) copolymers were successfully synthesized via radical solution polymerization, and PEDOT-coated P(SS-co-St) (PEDOT:P(SS-co-St)) was synthesized via Fe ⁺ -catalyzed oxidative polymerization. PEDOT:P(SS-co-St) was characterized by nuclear magnetic resonance and Fourier transform infrared spectroscopies. The particle size and morphology of PEDOT:P(SS-co-St) were examined using transmission electron microscopy, dynamic light scattering, and zeta potential measurements. The maximum NIR-shielding efficiency of the film was 92.0% with 40% transmittance. The high solution stability of PEDOT:P(SS-co-St) make it an ideal candidate for heat-insulating materials that find application in semi-transparent heat-insulator-coated windows.

Original language	English
Article number	151
Journal	Coatings
Volume	9
Issue number	3
DOIs	https://doi.org/10.3390/coatings9030151
Publication status	Published - 2019

Bibliographical note

Publisher Copyright:
© 2019 by the authors.

All Science Journal Classification (ASJC) codes

Surfaces and Interfaces
Surfaces, Coatings and Films
Materials Chemistry

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10.3390/coatings9030151

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title = "Synthesis of solution-stable PEDOT-coated sulfonated polystyrene copolymer PEDOT:P(SS-co-St) particles for all-organic NIR-shielding films",

abstract = " We prepared poly(3,4-ethylenedioxythiophene) (PEDOT)-coated sulfonated polystyrene copolymer particles as efficient heat-shielding agents, which showed strong near-infrared (NIR) absorption, with high solid contents and good solution stability. The poly(styrene sulfonate-co-styrene) (P(SS-co-St)) copolymers were successfully synthesized via radical solution polymerization, and PEDOT-coated P(SS-co-St) (PEDOT:P(SS-co-St)) was synthesized via Fe + -catalyzed oxidative polymerization. PEDOT:P(SS-co-St) was characterized by nuclear magnetic resonance and Fourier transform infrared spectroscopies. The particle size and morphology of PEDOT:P(SS-co-St) were examined using transmission electron microscopy, dynamic light scattering, and zeta potential measurements. The maximum NIR-shielding efficiency of the film was 92.0% with 40% transmittance. The high solution stability of PEDOT:P(SS-co-St) make it an ideal candidate for heat-insulating materials that find application in semi-transparent heat-insulator-coated windows.",

keywords = "Conducting polymer, Core-shell particles, NIR shielding film, PEDOT, Poly(3,4-ethylenedioxythiophene), Polystyrene",

author = "Soeun Im and Chanil Park and Wonseok Cho and Jooyoung Kim and Minseok Jeong and Kim, {Jung Hyun}",

note = "Publisher Copyright: {\textcopyright} 2019 by the authors.",

year = "2019",

doi = "10.3390/coatings9030151",

language = "English",

volume = "9",

journal = "Coatings",

issn = "2079-6412",

publisher = "Multidisciplinary Digital Publishing Institute (MDPI)",

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T1 - Synthesis of solution-stable PEDOT-coated sulfonated polystyrene copolymer PEDOT:P(SS-co-St) particles for all-organic NIR-shielding films

AU - Im, Soeun

AU - Park, Chanil

AU - Cho, Wonseok

AU - Kim, Jooyoung

AU - Jeong, Minseok

AU - Kim, Jung Hyun

PY - 2019

Y1 - 2019

N2 - We prepared poly(3,4-ethylenedioxythiophene) (PEDOT)-coated sulfonated polystyrene copolymer particles as efficient heat-shielding agents, which showed strong near-infrared (NIR) absorption, with high solid contents and good solution stability. The poly(styrene sulfonate-co-styrene) (P(SS-co-St)) copolymers were successfully synthesized via radical solution polymerization, and PEDOT-coated P(SS-co-St) (PEDOT:P(SS-co-St)) was synthesized via Fe + -catalyzed oxidative polymerization. PEDOT:P(SS-co-St) was characterized by nuclear magnetic resonance and Fourier transform infrared spectroscopies. The particle size and morphology of PEDOT:P(SS-co-St) were examined using transmission electron microscopy, dynamic light scattering, and zeta potential measurements. The maximum NIR-shielding efficiency of the film was 92.0% with 40% transmittance. The high solution stability of PEDOT:P(SS-co-St) make it an ideal candidate for heat-insulating materials that find application in semi-transparent heat-insulator-coated windows.

AB - We prepared poly(3,4-ethylenedioxythiophene) (PEDOT)-coated sulfonated polystyrene copolymer particles as efficient heat-shielding agents, which showed strong near-infrared (NIR) absorption, with high solid contents and good solution stability. The poly(styrene sulfonate-co-styrene) (P(SS-co-St)) copolymers were successfully synthesized via radical solution polymerization, and PEDOT-coated P(SS-co-St) (PEDOT:P(SS-co-St)) was synthesized via Fe + -catalyzed oxidative polymerization. PEDOT:P(SS-co-St) was characterized by nuclear magnetic resonance and Fourier transform infrared spectroscopies. The particle size and morphology of PEDOT:P(SS-co-St) were examined using transmission electron microscopy, dynamic light scattering, and zeta potential measurements. The maximum NIR-shielding efficiency of the film was 92.0% with 40% transmittance. The high solution stability of PEDOT:P(SS-co-St) make it an ideal candidate for heat-insulating materials that find application in semi-transparent heat-insulator-coated windows.

KW - Conducting polymer

KW - Core-shell particles

KW - NIR shielding film

KW - PEDOT

KW - Poly(3,4-ethylenedioxythiophene)

KW - Polystyrene

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Synthesis of solution-stable PEDOT-coated sulfonated polystyrene copolymer PEDOT:P(SS-co-St) particles for all-organic NIR-shielding films

Abstract

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