Synthesis of Jatropha Curcas biodiesel and physicochemical investigation of molecular interactions in Jatropha Curcas biodiesel + C2-C 3-alkanol blends

Satish Kumar; Wonsub Lim; Vinod Kumar Sharma; Sunil Kumar Garg; Il Moon

doi:10.1016/j.molliq.2013.01.026

Synthesis of Jatropha Curcas biodiesel and physicochemical investigation of molecular interactions in Jatropha Curcas biodiesel + C₂-C ₃-alkanol blends

Satish Kumar, Wonsub Lim, Vinod Kumar Sharma, Sunil Kumar Garg, Il Moon

Department of Chemical and Biomolecular Engineering

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

The physicochemical properties such as densities and speeds of sound have been measured for Jatropha Curcas biodiesel (1) + ethan-1-ol or propan-1-ol (2) binary mixtures over entire composition range at T = (288.15 to 308.15) K and atmospheric pressure. The measured data have been utilized to determine excess molar volumes V₁₂^E, isentropic compressibilities (κ_S)₁₂, and deviations in isentropic compressibilities (Δκ_S)₁₂. The V ₁₂^E and (Δκ_S)₁₂ values were fitted to Redlich-Kister polynomial equation to calculate the adjustable parameters together with their standard deviations. The measured data and derived physical properties have been discussed in terms of the dipole-dipole, dipole induced-dipole interactions, and hydrogen bonding between fatty acid methyl esters (biodiesel) and ethan-1-ol or propan-1-ol molecules and their structural factors.

Original language	English
Pages (from-to)	55-61
Number of pages	7
Journal	Journal of Molecular Liquids
Volume	181
DOIs	https://doi.org/10.1016/j.molliq.2013.01.026
Publication status	Published - 2013 May

Bibliographical note

Funding Information:
This work was supported by the Ministry of Education (MOE) of Korea through its BK21 Program and GAS plant R&D Centre funded by the Ministry of Land, Transportation and Maritime Affairs (MLTM) of Korean Government.

All Science Journal Classification (ASJC) codes

Electronic, Optical and Magnetic Materials
Atomic and Molecular Physics, and Optics
Condensed Matter Physics
Spectroscopy
Physical and Theoretical Chemistry
Materials Chemistry

Access to Document

10.1016/j.molliq.2013.01.026

Cite this

@article{bd497f410bc74e87b4514db4c346fa74,

title = "Synthesis of Jatropha Curcas biodiesel and physicochemical investigation of molecular interactions in Jatropha Curcas biodiesel + C2-C 3-alkanol blends",

abstract = "The physicochemical properties such as densities and speeds of sound have been measured for Jatropha Curcas biodiesel (1) + ethan-1-ol or propan-1-ol (2) binary mixtures over entire composition range at T = (288.15 to 308.15) K and atmospheric pressure. The measured data have been utilized to determine excess molar volumes V12E, isentropic compressibilities (κS)12, and deviations in isentropic compressibilities (ΔκS)12. The V 12E and (ΔκS)12 values were fitted to Redlich-Kister polynomial equation to calculate the adjustable parameters together with their standard deviations. The measured data and derived physical properties have been discussed in terms of the dipole-dipole, dipole induced-dipole interactions, and hydrogen bonding between fatty acid methyl esters (biodiesel) and ethan-1-ol or propan-1-ol molecules and their structural factors.",

author = "Satish Kumar and Wonsub Lim and {Kumar Sharma}, Vinod and {Kumar Garg}, Sunil and Il Moon",

note = "Funding Information: This work was supported by the Ministry of Education (MOE) of Korea through its BK21 Program and GAS plant R&D Centre funded by the Ministry of Land, Transportation and Maritime Affairs (MLTM) of Korean Government.",

year = "2013",

month = may,

doi = "10.1016/j.molliq.2013.01.026",

language = "English",

volume = "181",

pages = "55--61",

journal = "Journal of Molecular Liquids",

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AU - Kumar, Satish

AU - Lim, Wonsub

AU - Kumar Sharma, Vinod

AU - Kumar Garg, Sunil

AU - Moon, Il

N1 - Funding Information: This work was supported by the Ministry of Education (MOE) of Korea through its BK21 Program and GAS plant R&D Centre funded by the Ministry of Land, Transportation and Maritime Affairs (MLTM) of Korean Government.

PY - 2013/5

Y1 - 2013/5

N2 - The physicochemical properties such as densities and speeds of sound have been measured for Jatropha Curcas biodiesel (1) + ethan-1-ol or propan-1-ol (2) binary mixtures over entire composition range at T = (288.15 to 308.15) K and atmospheric pressure. The measured data have been utilized to determine excess molar volumes V12E, isentropic compressibilities (κS)12, and deviations in isentropic compressibilities (ΔκS)12. The V 12E and (ΔκS)12 values were fitted to Redlich-Kister polynomial equation to calculate the adjustable parameters together with their standard deviations. The measured data and derived physical properties have been discussed in terms of the dipole-dipole, dipole induced-dipole interactions, and hydrogen bonding between fatty acid methyl esters (biodiesel) and ethan-1-ol or propan-1-ol molecules and their structural factors.

AB - The physicochemical properties such as densities and speeds of sound have been measured for Jatropha Curcas biodiesel (1) + ethan-1-ol or propan-1-ol (2) binary mixtures over entire composition range at T = (288.15 to 308.15) K and atmospheric pressure. The measured data have been utilized to determine excess molar volumes V12E, isentropic compressibilities (κS)12, and deviations in isentropic compressibilities (ΔκS)12. The V 12E and (ΔκS)12 values were fitted to Redlich-Kister polynomial equation to calculate the adjustable parameters together with their standard deviations. The measured data and derived physical properties have been discussed in terms of the dipole-dipole, dipole induced-dipole interactions, and hydrogen bonding between fatty acid methyl esters (biodiesel) and ethan-1-ol or propan-1-ol molecules and their structural factors.

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