Synthesis of cobalt cluster-based supramolecular triple-stranded helicates

Hyojong Yoo; Jeonghee Lee; Philjae Kang; Moon Gun Choi

doi:10.1039/c5dt01895a

Synthesis of cobalt cluster-based supramolecular triple-stranded helicates

Hyojong Yoo, Jeonghee Lee, Philjae Kang, Moon Gun Choi

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

16 Citations (Scopus)

Abstract

A cobalt cluster-based triple-stranded helicate, Co₈(PDA)₆(PTA)₃(DMF)₃(H₂O)₃ (1) (PDA = 2,6-pyridinedicarboxylate, PTA = benzene-1,3-dicarboxylate, DMF = dimethylformamide) was successfully synthesized and fully characterized. Complex 1 can be used as a supramolecular building block in constructing a higher-order helix-of-helix structure, [Co₈(PDA)₆(PTA)₃(DMF)₂(H₂O)₄-0.51(Co(OH_n)₂)] (n = 1 or 2) (2).

Original language	English
Pages (from-to)	14213-14216
Number of pages	4
Journal	Dalton Transactions
Volume	44
Issue number	32
DOIs	https://doi.org/10.1039/c5dt01895a
Publication status	Published - 2015 Aug 28

Bibliographical note

Publisher Copyright:
© The Royal Society of Chemistry 2015.

All Science Journal Classification (ASJC) codes

Inorganic Chemistry

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10.1039/c5dt01895a

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title = "Synthesis of cobalt cluster-based supramolecular triple-stranded helicates",

abstract = "A cobalt cluster-based triple-stranded helicate, Co8(PDA)6(PTA)3(DMF)3(H2O)3 (1) (PDA = 2,6-pyridinedicarboxylate, PTA = benzene-1,3-dicarboxylate, DMF = dimethylformamide) was successfully synthesized and fully characterized. Complex 1 can be used as a supramolecular building block in constructing a higher-order helix-of-helix structure, [Co8(PDA)6(PTA)3(DMF)2(H2O)4-0.51(Co(OHn)2)] (n = 1 or 2) (2).",

author = "Hyojong Yoo and Jeonghee Lee and Philjae Kang and Choi, {Moon Gun}",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2015.",

year = "2015",

month = aug,

day = "28",

doi = "10.1039/c5dt01895a",

language = "English",

volume = "44",

pages = "14213--14216",

journal = "Dalton Transactions",

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publisher = "Royal Society of Chemistry",

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T1 - Synthesis of cobalt cluster-based supramolecular triple-stranded helicates

AU - Yoo, Hyojong

AU - Lee, Jeonghee

AU - Kang, Philjae

AU - Choi, Moon Gun

PY - 2015/8/28

Y1 - 2015/8/28

N2 - A cobalt cluster-based triple-stranded helicate, Co8(PDA)6(PTA)3(DMF)3(H2O)3 (1) (PDA = 2,6-pyridinedicarboxylate, PTA = benzene-1,3-dicarboxylate, DMF = dimethylformamide) was successfully synthesized and fully characterized. Complex 1 can be used as a supramolecular building block in constructing a higher-order helix-of-helix structure, [Co8(PDA)6(PTA)3(DMF)2(H2O)4-0.51(Co(OHn)2)] (n = 1 or 2) (2).

AB - A cobalt cluster-based triple-stranded helicate, Co8(PDA)6(PTA)3(DMF)3(H2O)3 (1) (PDA = 2,6-pyridinedicarboxylate, PTA = benzene-1,3-dicarboxylate, DMF = dimethylformamide) was successfully synthesized and fully characterized. Complex 1 can be used as a supramolecular building block in constructing a higher-order helix-of-helix structure, [Co8(PDA)6(PTA)3(DMF)2(H2O)4-0.51(Co(OHn)2)] (n = 1 or 2) (2).

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U2 - 10.1039/c5dt01895a

DO - 10.1039/c5dt01895a

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JO - Dalton Transactions

JF - Dalton Transactions

IS - 32

ER -

Synthesis of cobalt cluster-based supramolecular triple-stranded helicates

Abstract

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