Synthesis of aliphatic ketones from allylic alcohols through consecutive isomerization and chelation-assisted hydroacylation by a rhodium catalyst

Dae Yon Lee; Choong Woon Moon; Chul Ho Jun

doi:10.1021/jo025541g

Synthesis of aliphatic ketones from allylic alcohols through consecutive isomerization and chelation-assisted hydroacylation by a rhodium catalyst

Dae Yon Lee, Choong Woon Moon, Chul Ho Jun

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

35 Citations (Scopus)

Abstract

Abstract: An allylic alcohol, utilized as a precursor for an aliphatic aldehyde, reacted with olefins to afford aliphatic ketones in the presence of RhCl(PPh₃)3, 2-amino-4-picoline, aniline, and benzoic acid through a tandem reaction of an isomerization and a chelation-assisted hydroacylation.

Original language	English
Pages (from-to)	3945-3948
Number of pages	4
Journal	Journal of Organic Chemistry
Volume	67
Issue number	11
DOIs	https://doi.org/10.1021/jo025541g
Publication status	Published - 2002 May 31

All Science Journal Classification (ASJC) codes

Organic Chemistry

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10.1021/jo025541g

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title = "Synthesis of aliphatic ketones from allylic alcohols through consecutive isomerization and chelation-assisted hydroacylation by a rhodium catalyst",

abstract = "Abstract: An allylic alcohol, utilized as a precursor for an aliphatic aldehyde, reacted with olefins to afford aliphatic ketones in the presence of RhCl(PPh3)3, 2-amino-4-picoline, aniline, and benzoic acid through a tandem reaction of an isomerization and a chelation-assisted hydroacylation.",

author = "Lee, {Dae Yon} and Moon, {Choong Woon} and Jun, {Chul Ho}",

year = "2002",

month = may,

day = "31",

doi = "10.1021/jo025541g",

language = "English",

volume = "67",

pages = "3945--3948",

journal = "Journal of Organic Chemistry",

issn = "0022-3263",

publisher = "American Chemical Society",

number = "11",

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TY - JOUR

T1 - Synthesis of aliphatic ketones from allylic alcohols through consecutive isomerization and chelation-assisted hydroacylation by a rhodium catalyst

AU - Lee, Dae Yon

AU - Moon, Choong Woon

AU - Jun, Chul Ho

PY - 2002/5/31

Y1 - 2002/5/31

N2 - Abstract: An allylic alcohol, utilized as a precursor for an aliphatic aldehyde, reacted with olefins to afford aliphatic ketones in the presence of RhCl(PPh3)3, 2-amino-4-picoline, aniline, and benzoic acid through a tandem reaction of an isomerization and a chelation-assisted hydroacylation.

AB - Abstract: An allylic alcohol, utilized as a precursor for an aliphatic aldehyde, reacted with olefins to afford aliphatic ketones in the presence of RhCl(PPh3)3, 2-amino-4-picoline, aniline, and benzoic acid through a tandem reaction of an isomerization and a chelation-assisted hydroacylation.

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U2 - 10.1021/jo025541g

DO - 10.1021/jo025541g

M3 - Article

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AN - SCOPUS:0037205035

SN - 0022-3263

VL - 67

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JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

IS - 11

ER -

Synthesis of aliphatic ketones from allylic alcohols through consecutive isomerization and chelation-assisted hydroacylation by a rhodium catalyst

Abstract

All Science Journal Classification (ASJC) codes

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