Synthesis of 6-, 7- and 8-membered cyclosiloxanes having multifunctional groups

Hyeon Mo Cho; Ji Eun Lee; Myong Euy Lee; Kang Mun Lee

doi:10.1016/j.jorganchem.2011.04.025

Synthesis of 6-, 7- and 8-membered cyclosiloxanes having multifunctional groups

Hyeon Mo Cho, Ji Eun Lee, Myong Euy Lee, Kang Mun Lee

University College

Research output: Contribution to journal › Short survey › peer-review

4 Citations (Scopus)

Abstract

Cyclosiloxanes having intramolecular donor atoms, a Si-Si bond, and vinyl groups were synthesized as useful precursors for ring-opening polymerization. 1,1,3,3-Tetrakis(dimethylaminomethylphenyl)-5,5-dimethylcyclotrisiloxane was also synthesized and characterized by single crystal X-ray structural analysis, which shows strong coordination from N to Si in the solid state.

Original language	English
Pages (from-to)	2754-2757
Number of pages	4
Journal	Journal of Organometallic Chemistry
Volume	696
Issue number	14
DOIs	https://doi.org/10.1016/j.jorganchem.2011.04.025
Publication status	Published - 2011 Jul 15

Bibliographical note

Funding Information:
This research was supported by a grant from the Fundamental R&D Program for Core Technology of Materials funded by the Ministry of Knowledge Economy , Republic of Korea.

All Science Journal Classification (ASJC) codes

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/j.jorganchem.2011.04.025

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@article{84a0911960b0454d878ab98977032298,

title = "Synthesis of 6-, 7- and 8-membered cyclosiloxanes having multifunctional groups",

abstract = "Cyclosiloxanes having intramolecular donor atoms, a Si-Si bond, and vinyl groups were synthesized as useful precursors for ring-opening polymerization. 1,1,3,3-Tetrakis(dimethylaminomethylphenyl)-5,5-dimethylcyclotrisiloxane was also synthesized and characterized by single crystal X-ray structural analysis, which shows strong coordination from N to Si in the solid state.",

keywords = "Cyclic siloxane, Intramolecular donor atom, Organosilicon compound, Si-Si bond, Vinylsiloxane",

author = "Cho, {Hyeon Mo} and Lee, {Ji Eun} and Lee, {Myong Euy} and Lee, {Kang Mun}",

note = "Funding Information: This research was supported by a grant from the Fundamental R&D Program for Core Technology of Materials funded by the Ministry of Knowledge Economy , Republic of Korea. ",

year = "2011",

month = jul,

day = "15",

doi = "10.1016/j.jorganchem.2011.04.025",

language = "English",

volume = "696",

pages = "2754--2757",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier B.V.",

number = "14",

}

TY - JOUR

T1 - Synthesis of 6-, 7- and 8-membered cyclosiloxanes having multifunctional groups

AU - Cho, Hyeon Mo

AU - Lee, Ji Eun

AU - Lee, Myong Euy

AU - Lee, Kang Mun

N1 - Funding Information: This research was supported by a grant from the Fundamental R&D Program for Core Technology of Materials funded by the Ministry of Knowledge Economy , Republic of Korea.

PY - 2011/7/15

Y1 - 2011/7/15

N2 - Cyclosiloxanes having intramolecular donor atoms, a Si-Si bond, and vinyl groups were synthesized as useful precursors for ring-opening polymerization. 1,1,3,3-Tetrakis(dimethylaminomethylphenyl)-5,5-dimethylcyclotrisiloxane was also synthesized and characterized by single crystal X-ray structural analysis, which shows strong coordination from N to Si in the solid state.

AB - Cyclosiloxanes having intramolecular donor atoms, a Si-Si bond, and vinyl groups were synthesized as useful precursors for ring-opening polymerization. 1,1,3,3-Tetrakis(dimethylaminomethylphenyl)-5,5-dimethylcyclotrisiloxane was also synthesized and characterized by single crystal X-ray structural analysis, which shows strong coordination from N to Si in the solid state.

KW - Cyclic siloxane

KW - Intramolecular donor atom

KW - Organosilicon compound

KW - Si-Si bond

KW - Vinylsiloxane

UR - http://www.scopus.com/inward/record.url?scp=79958049729&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=79958049729&partnerID=8YFLogxK

U2 - 10.1016/j.jorganchem.2011.04.025

DO - 10.1016/j.jorganchem.2011.04.025

M3 - Short survey

AN - SCOPUS:79958049729

SN - 0022-328X

VL - 696

SP - 2754

EP - 2757

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 14

ER -

Synthesis of 6-, 7- and 8-membered cyclosiloxanes having multifunctional groups

Abstract

Bibliographical note

All Science Journal Classification (ASJC) codes

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