Synthesis of 2,3-Di- and 2,3,4-trisubstituted furans from 1,2-dioxines generated by an enyne-RCM/Diels-Alder reaction sequence

Young Keun Yang; Jung Hoon Choi; Jinsung Tae

doi:10.1021/jo050957q

Synthesis of 2,3-Di- and 2,3,4-trisubstituted furans from 1,2-dioxines generated by an enyne-RCM/Diels-Alder reaction sequence

Young Keun Yang, Jung Hoon Choi, Jinsung Tae

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

46 Citations (Scopus)

Abstract

An efficient method for the synthesis of 2,3- and 2,3,4-substituted furans starting from acyclic enynes was developed using an enyne-RCM/Diels-Alder reaction sequence. The reaction conditions for the transformation of 1,2-dioxines having an adjacent 1,2-oxazine ring into furans and the cleavage of N-O bonds are discussed.

Original language	English
Pages (from-to)	6995-6998
Number of pages	4
Journal	Journal of Organic Chemistry
Volume	70
Issue number	17
DOIs	https://doi.org/10.1021/jo050957q
Publication status	Published - 2005 Aug 19

All Science Journal Classification (ASJC) codes

Organic Chemistry

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10.1021/jo050957q

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abstract = "An efficient method for the synthesis of 2,3- and 2,3,4-substituted furans starting from acyclic enynes was developed using an enyne-RCM/Diels-Alder reaction sequence. The reaction conditions for the transformation of 1,2-dioxines having an adjacent 1,2-oxazine ring into furans and the cleavage of N-O bonds are discussed.",

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AU - Yang, Young Keun

AU - Choi, Jung Hoon

AU - Tae, Jinsung

PY - 2005/8/19

Y1 - 2005/8/19

N2 - An efficient method for the synthesis of 2,3- and 2,3,4-substituted furans starting from acyclic enynes was developed using an enyne-RCM/Diels-Alder reaction sequence. The reaction conditions for the transformation of 1,2-dioxines having an adjacent 1,2-oxazine ring into furans and the cleavage of N-O bonds are discussed.

AB - An efficient method for the synthesis of 2,3- and 2,3,4-substituted furans starting from acyclic enynes was developed using an enyne-RCM/Diels-Alder reaction sequence. The reaction conditions for the transformation of 1,2-dioxines having an adjacent 1,2-oxazine ring into furans and the cleavage of N-O bonds are discussed.

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Synthesis of 2,3-Di- and 2,3,4-trisubstituted furans from 1,2-dioxines generated by an enyne-RCM/Diels-Alder reaction sequence

Abstract

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