Synthesis and structure of the monolayer hydrate K0.3CoO 2·0.4H2O

S. Park; Y. Lee; W. Si; T. Vogt

doi:10.1016/j.ssc.2005.03.007

Synthesis and structure of the monolayer hydrate K_0.3CoO ₂·0.4H₂O

S. Park, Y. Lee, W. Si, T. Vogt

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

The monolayer hydrate (MLH) K_0.3CoO₂·0.4H ₂O was synthesized from K_0.6CoO₂ by extracting K⁺ cations using K₂S₂O₈ as an oxidant and the subsequent intercalation of water between the layers of edge-sharing CoO₆ octahedra. A hexagonal structure (space group P6₃/mmc) with lattice parameters a=2.8262(1) Å, c=13.8269(6) Å similar to the MLH Na_0.36CoO₂·0.7H ₂O was established using high-resolution synchrotron X-ray powder diffraction data. The K/H₂O layer in the K-MLH is disordered, which is in contrast to the Na-MLH. At low temperatures metallic and paramagnetic behavior was found.

Original language	English
Pages (from-to)	607-611
Number of pages	5
Journal	Solid State Communications
Volume	134
Issue number	9
DOIs	https://doi.org/10.1016/j.ssc.2005.03.007
Publication status	Published - 2005 Jun

Bibliographical note

Funding Information:
This work was supported by an LDRD from BNL. Research carried out in part at the NSLS at BNL is supported by the US DOE (DE-Ac02-98CH10886 for beam line X7A).

All Science Journal Classification (ASJC) codes

Chemistry(all)
Condensed Matter Physics
Materials Chemistry

Access to Document

10.1016/j.ssc.2005.03.007

Cite this

@article{44833712a956403aa7cd4bcf919950d9,

title = "Synthesis and structure of the monolayer hydrate K0.3CoO 2·0.4H2O",

abstract = "The monolayer hydrate (MLH) K0.3CoO2·0.4H 2O was synthesized from K0.6CoO2 by extracting K+ cations using K2S2O8 as an oxidant and the subsequent intercalation of water between the layers of edge-sharing CoO6 octahedra. A hexagonal structure (space group P63/mmc) with lattice parameters a=2.8262(1) {\AA}, c=13.8269(6) {\AA} similar to the MLH Na0.36CoO2·0.7H 2O was established using high-resolution synchrotron X-ray powder diffraction data. The K/H2O layer in the K-MLH is disordered, which is in contrast to the Na-MLH. At low temperatures metallic and paramagnetic behavior was found.",

author = "S. Park and Y. Lee and W. Si and T. Vogt",

note = "Funding Information: This work was supported by an LDRD from BNL. Research carried out in part at the NSLS at BNL is supported by the US DOE (DE-Ac02-98CH10886 for beam line X7A). ",

year = "2005",

month = jun,

doi = "10.1016/j.ssc.2005.03.007",

language = "English",

volume = "134",

pages = "607--611",

journal = "Solid State Communications",

issn = "0038-1098",

publisher = "Elsevier Limited",

number = "9",

}

TY - JOUR

T1 - Synthesis and structure of the monolayer hydrate K0.3CoO 2·0.4H2O

AU - Park, S.

AU - Lee, Y.

AU - Si, W.

AU - Vogt, T.

N1 - Funding Information: This work was supported by an LDRD from BNL. Research carried out in part at the NSLS at BNL is supported by the US DOE (DE-Ac02-98CH10886 for beam line X7A).

PY - 2005/6

Y1 - 2005/6

N2 - The monolayer hydrate (MLH) K0.3CoO2·0.4H 2O was synthesized from K0.6CoO2 by extracting K+ cations using K2S2O8 as an oxidant and the subsequent intercalation of water between the layers of edge-sharing CoO6 octahedra. A hexagonal structure (space group P63/mmc) with lattice parameters a=2.8262(1) Å, c=13.8269(6) Å similar to the MLH Na0.36CoO2·0.7H 2O was established using high-resolution synchrotron X-ray powder diffraction data. The K/H2O layer in the K-MLH is disordered, which is in contrast to the Na-MLH. At low temperatures metallic and paramagnetic behavior was found.

AB - The monolayer hydrate (MLH) K0.3CoO2·0.4H 2O was synthesized from K0.6CoO2 by extracting K+ cations using K2S2O8 as an oxidant and the subsequent intercalation of water between the layers of edge-sharing CoO6 octahedra. A hexagonal structure (space group P63/mmc) with lattice parameters a=2.8262(1) Å, c=13.8269(6) Å similar to the MLH Na0.36CoO2·0.7H 2O was established using high-resolution synchrotron X-ray powder diffraction data. The K/H2O layer in the K-MLH is disordered, which is in contrast to the Na-MLH. At low temperatures metallic and paramagnetic behavior was found.

UR - http://www.scopus.com/inward/record.url?scp=17644410741&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=17644410741&partnerID=8YFLogxK

U2 - 10.1016/j.ssc.2005.03.007

DO - 10.1016/j.ssc.2005.03.007

M3 - Article

AN - SCOPUS:17644410741

SN - 0038-1098

VL - 134

SP - 607

EP - 611

JO - Solid State Communications

JF - Solid State Communications

IS - 9

ER -