Synthesis and structure of the bilayer hydrate Na0.3NiO 2·1.3D2O

Sangmoon Park; Yongjae Lee; Margaret Elcombe; Thomas Vogt

doi:10.1021/ic060235x

Synthesis and structure of the bilayer hydrate Na_0.3NiO ₂·1.3D₂O

Sangmoon Park, Yongjae Lee, Margaret Elcombe, Thomas Vogt

Research output: Contribution to journal › Article › peer-review

17 Citations (Scopus)

Abstract

The metal oxide bilayer deuterate (hydrate) Na_0.3NiO ₂·1.3D₂O (Na_0.3NiO₂·1. 3H₂O) were prepared from Na_xNiO₂ by extracting Na⁺ cations and simultaneously intercalating fully and nondeuterated water. High-resolution neutron powder diffraction, thermogravimetric analysis, and inductively coupled plasma atomic emission spectroscopy were used to show that a Na_0.3(D₂O)_1.3 network separates layers of edge-sharing NiO₆ octahedra.

Original language	English
Pages (from-to)	3490-3492
Number of pages	3
Journal	Inorganic Chemistry
Volume	45
Issue number	9
DOIs	https://doi.org/10.1021/ic060235x
Publication status	Published - 2006 May 1

All Science Journal Classification (ASJC) codes

Physical and Theoretical Chemistry
Inorganic Chemistry

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title = "Synthesis and structure of the bilayer hydrate Na0.3NiO 2·1.3D2O",

abstract = "The metal oxide bilayer deuterate (hydrate) Na0.3NiO 2·1.3D2O (Na0.3NiO2·1. 3H2O) were prepared from NaxNiO2 by extracting Na+ cations and simultaneously intercalating fully and nondeuterated water. High-resolution neutron powder diffraction, thermogravimetric analysis, and inductively coupled plasma atomic emission spectroscopy were used to show that a Na0.3(D2O)1.3 network separates layers of edge-sharing NiO6 octahedra.",

author = "Sangmoon Park and Yongjae Lee and Margaret Elcombe and Thomas Vogt",

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T1 - Synthesis and structure of the bilayer hydrate Na0.3NiO 2·1.3D2O

AU - Park, Sangmoon

AU - Lee, Yongjae

AU - Elcombe, Margaret

AU - Vogt, Thomas

PY - 2006/5/1

Y1 - 2006/5/1

N2 - The metal oxide bilayer deuterate (hydrate) Na0.3NiO 2·1.3D2O (Na0.3NiO2·1. 3H2O) were prepared from NaxNiO2 by extracting Na+ cations and simultaneously intercalating fully and nondeuterated water. High-resolution neutron powder diffraction, thermogravimetric analysis, and inductively coupled plasma atomic emission spectroscopy were used to show that a Na0.3(D2O)1.3 network separates layers of edge-sharing NiO6 octahedra.

AB - The metal oxide bilayer deuterate (hydrate) Na0.3NiO 2·1.3D2O (Na0.3NiO2·1. 3H2O) were prepared from NaxNiO2 by extracting Na+ cations and simultaneously intercalating fully and nondeuterated water. High-resolution neutron powder diffraction, thermogravimetric analysis, and inductively coupled plasma atomic emission spectroscopy were used to show that a Na0.3(D2O)1.3 network separates layers of edge-sharing NiO6 octahedra.

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JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 9

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Synthesis and structure of the bilayer hydrate Na_0.3NiO ₂·1.3D₂O

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