Synthesis and reactivity of stable trisyl(aminomethylphenyl)silylenoid

Hyeon Mo Cho; Young Mook Lim; Byung Wook Lee; Sung Jin Park; Myong Euy Lee

doi:10.1016/j.jorganchem.2011.03.032

Synthesis and reactivity of stable trisyl(aminomethylphenyl)silylenoid

Hyeon Mo Cho, Young Mook Lim, Byung Wook Lee, Sung Jin Park, Myong Euy Lee

University College

Research output: Contribution to journal › Article › peer-review

19 Citations (Scopus)

Abstract

A highly thermally stable silylenoid, trisyl(aminomethylphenyl)silylenoid (2) was synthesized from the reaction of dimethylaminomethylphenyllithium with a bromosilylenoid, 1. Silylenoid 2 reacted with electrophiles to give the corresponding products, but did not react with alkyllithiums as a nucleophile.

Original language	English
Pages (from-to)	2665-2668
Number of pages	4
Journal	Journal of Organometallic Chemistry
Volume	696
Issue number	13
DOIs	https://doi.org/10.1016/j.jorganchem.2011.03.032
Publication status	Published - 2011 Jul 1

Bibliographical note

Funding Information:
This research was supported by Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education, Science and Technology ( 2010-0024877 ). The authors thank Professor Robert West, distinguished professor in WCU (World Class University, R33-10082) program through the National Research Foundation of Korea funded by the Ministry of Education, Science and Technology for his valuable discussion.

All Science Journal Classification (ASJC) codes

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/j.jorganchem.2011.03.032

Cite this

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title = "Synthesis and reactivity of stable trisyl(aminomethylphenyl)silylenoid",

abstract = "A highly thermally stable silylenoid, trisyl(aminomethylphenyl)silylenoid (2) was synthesized from the reaction of dimethylaminomethylphenyllithium with a bromosilylenoid, 1. Silylenoid 2 reacted with electrophiles to give the corresponding products, but did not react with alkyllithiums as a nucleophile.",

author = "Cho, {Hyeon Mo} and Lim, {Young Mook} and Lee, {Byung Wook} and Park, {Sung Jin} and Lee, {Myong Euy}",

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AU - Lim, Young Mook

AU - Lee, Byung Wook

AU - Park, Sung Jin

AU - Lee, Myong Euy

N1 - Funding Information: This research was supported by Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education, Science and Technology ( 2010-0024877 ). The authors thank Professor Robert West, distinguished professor in WCU (World Class University, R33-10082) program through the National Research Foundation of Korea funded by the Ministry of Education, Science and Technology for his valuable discussion.

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AB - A highly thermally stable silylenoid, trisyl(aminomethylphenyl)silylenoid (2) was synthesized from the reaction of dimethylaminomethylphenyllithium with a bromosilylenoid, 1. Silylenoid 2 reacted with electrophiles to give the corresponding products, but did not react with alkyllithiums as a nucleophile.

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Synthesis and reactivity of stable trisyl(aminomethylphenyl)silylenoid

Abstract

Bibliographical note

All Science Journal Classification (ASJC) codes

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