Synthesis and photochromism of polymer-bound phenoxyquinone derivatives

Sang Yong Ju; Dae Ik Kwon; Sung Jun Min; Kwang Duk Ahn; Ki Hong Park; Jong Man Kim

doi:10.1016/S1010-6030(03)00211-9

Synthesis and photochromism of polymer-bound phenoxyquinone derivatives

Sang Yong Ju, Dae Ik Kwon, Sung Jun Min, Kwang Duk Ahn, Ki Hong Park, Jong Man Kim

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

Acrylate- and styrene-derived polymers having pendant phenoxyquinones for photochromism were prepared by 2,2′-azoisobutyronitrile (AIBN)-initiated radical polymerization. Synthesis of the monomers were straightforward and the polymers were obtained in high yields in spite of the quinone moieties presented in the monomers, which usually can function as radical scavengers and/or catalysts poison. Photo-induced rearrangement from the " trans "-quinone forms to the " ana "-quinone forms readily occurred when the polymer films were irradiated with UV light.

Original language	English
Pages (from-to)	151-157
Number of pages	7
Journal	Journal of Photochemistry and Photobiology A: Chemistry
Volume	160
Issue number	3
DOIs	https://doi.org/10.1016/S1010-6030(03)00211-9
Publication status	Published - 2003 Aug 21

Bibliographical note

Funding Information:
This research was supported by Korea Research Foundation Grant (KRF-2001-003-E00301).

All Science Journal Classification (ASJC) codes

Chemistry(all)
Chemical Engineering(all)
Physics and Astronomy(all)

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10.1016/S1010-6030(03)00211-9

Cite this

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abstract = "Acrylate- and styrene-derived polymers having pendant phenoxyquinones for photochromism were prepared by 2,2′-azoisobutyronitrile (AIBN)-initiated radical polymerization. Synthesis of the monomers were straightforward and the polymers were obtained in high yields in spite of the quinone moieties presented in the monomers, which usually can function as radical scavengers and/or catalysts poison. Photo-induced rearrangement from the {"} trans {"}-quinone forms to the {"} ana {"}-quinone forms readily occurred when the polymer films were irradiated with UV light.",

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T1 - Synthesis and photochromism of polymer-bound phenoxyquinone derivatives

AU - Ju, Sang Yong

AU - Kwon, Dae Ik

AU - Min, Sung Jun

AU - Ahn, Kwang Duk

AU - Park, Ki Hong

AU - Kim, Jong Man

N1 - Funding Information: This research was supported by Korea Research Foundation Grant (KRF-2001-003-E00301).

PY - 2003/8/21

Y1 - 2003/8/21

N2 - Acrylate- and styrene-derived polymers having pendant phenoxyquinones for photochromism were prepared by 2,2′-azoisobutyronitrile (AIBN)-initiated radical polymerization. Synthesis of the monomers were straightforward and the polymers were obtained in high yields in spite of the quinone moieties presented in the monomers, which usually can function as radical scavengers and/or catalysts poison. Photo-induced rearrangement from the " trans "-quinone forms to the " ana "-quinone forms readily occurred when the polymer films were irradiated with UV light.

AB - Acrylate- and styrene-derived polymers having pendant phenoxyquinones for photochromism were prepared by 2,2′-azoisobutyronitrile (AIBN)-initiated radical polymerization. Synthesis of the monomers were straightforward and the polymers were obtained in high yields in spite of the quinone moieties presented in the monomers, which usually can function as radical scavengers and/or catalysts poison. Photo-induced rearrangement from the " trans "-quinone forms to the " ana "-quinone forms readily occurred when the polymer films were irradiated with UV light.

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Synthesis and photochromism of polymer-bound phenoxyquinone derivatives

Abstract

Bibliographical note

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