TY - JOUR
T1 - Synthesis and Mesomorphic Properties of Palladium (II) Complexes Based on 3,4,5-Trialkoxy Benzonitrile Ligands
AU - Lee, Myongsoo
AU - Yoo, Yong Sik
AU - Choi, Moon Gun
PY - 1997
Y1 - 1997
N2 - The synthesis and characterization of the nitrile ligands 3,4,5-tridodecyloxy benzonitrile (7) and 3,4,5-trioctadecyloxy bezonitrile (8), and their corresponding palladium(II) complexes are described. The nitrile ligands display only a crystalline phase and do not show liquid crystalline behavior, while their corresponding palladium(II) complexes display an enantiotropic columnar mesophase. The induction of the columnar mesophase is mainly due to dimerization through the palladium complexation of the half disk-like nitrile ligands giving rise to a trans square planar geometry.
AB - The synthesis and characterization of the nitrile ligands 3,4,5-tridodecyloxy benzonitrile (7) and 3,4,5-trioctadecyloxy bezonitrile (8), and their corresponding palladium(II) complexes are described. The nitrile ligands display only a crystalline phase and do not show liquid crystalline behavior, while their corresponding palladium(II) complexes display an enantiotropic columnar mesophase. The induction of the columnar mesophase is mainly due to dimerization through the palladium complexation of the half disk-like nitrile ligands giving rise to a trans square planar geometry.
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M3 - Article
AN - SCOPUS:0031314165
SN - 0253-2964
VL - 18
SP - 1067
EP - 1070
JO - Bulletin of the Korean Chemical Society
JF - Bulletin of the Korean Chemical Society
IS - 10
ER -