Surface‐induced substitution reaction on cobalt(III) and manganese(III) tetrakis (4‐N‐methylpyridyl)porphyrins probed by surface‐enhanced Raman spectroscopy

Jong‐Seo ‐S Ha; Ok‐Keun ‐K Song; Minjoong Yoon; Dongho Kim

doi:10.1002/jrs.1250211006

Surface‐induced substitution reaction on cobalt(III) and manganese(III) tetrakis (4‐N‐methylpyridyl)porphyrins probed by surface‐enhanced Raman spectroscopy

Jong‐Seo ‐S Ha, Ok‐Keun ‐K Song, Minjoong Yoon, Dongho Kim

Department of Chemistry

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Abstract

The Surface‐enhanced Raman spectra of Co(III)TMPyP(4)Cl and Mn(III)TMPyP(4)Cl [where TMPyP(4) = tetrakis (4‐N‐methylpyridyl)porphyrin] demonstrate the formation of Ag(II)TMPyP(4) on the silver surface. The reaction is not photon assisted but is dependent on the sol activity and time. The effect of NaCl on the sol activity and the surface‐induced reaction was investigated. It was observed that the metal substitution reaction of Mn(III)TMPyP(4)Cl was more efficient than that of Co(III)TMPyP(4)Cl.

Original language	English
Pages (from-to)	667-674
Number of pages	8
Journal	Journal of Raman Spectroscopy
Volume	21
Issue number	10
DOIs	https://doi.org/10.1002/jrs.1250211006
Publication status	Published - 1990 Oct

All Science Journal Classification (ASJC) codes

Materials Science(all)
Spectroscopy

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@article{ed769238fac745d3bf72b00aafdc518b,

title = "Surface‐induced substitution reaction on cobalt(III) and manganese(III) tetrakis (4‐N‐methylpyridyl)porphyrins probed by surface‐enhanced Raman spectroscopy",

abstract = "The Surface‐enhanced Raman spectra of Co(III)TMPyP(4)Cl and Mn(III)TMPyP(4)Cl [where TMPyP(4) = tetrakis (4‐N‐methylpyridyl)porphyrin] demonstrate the formation of Ag(II)TMPyP(4) on the silver surface. The reaction is not photon assisted but is dependent on the sol activity and time. The effect of NaCl on the sol activity and the surface‐induced reaction was investigated. It was observed that the metal substitution reaction of Mn(III)TMPyP(4)Cl was more efficient than that of Co(III)TMPyP(4)Cl.",

author = "Ha, {Jong‐Seo ‐S} and Song, {Ok‐Keun ‐K} and Minjoong Yoon and Dongho Kim",

year = "1990",

month = oct,

doi = "10.1002/jrs.1250211006",

language = "English",

volume = "21",

pages = "667--674",

journal = "Journal of Raman Spectroscopy",

issn = "0377-0486",

publisher = "John Wiley and Sons Ltd",

number = "10",

}

Surface‐induced substitution reaction on cobalt(III) and manganese(III) tetrakis (4‐N‐methylpyridyl)porphyrins probed by surface‐enhanced Raman spectroscopy. / Ha, Jong‐Seo ‐S; Song, Ok‐Keun ‐K; Yoon, Minjoong et al.
In: Journal of Raman Spectroscopy, Vol. 21, No. 10, 10.1990, p. 667-674.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Surface‐induced substitution reaction on cobalt(III) and manganese(III) tetrakis (4‐N‐methylpyridyl)porphyrins probed by surface‐enhanced Raman spectroscopy

AU - Ha, Jong‐Seo ‐S

AU - Song, Ok‐Keun ‐K

AU - Yoon, Minjoong

AU - Kim, Dongho

PY - 1990/10

Y1 - 1990/10

N2 - The Surface‐enhanced Raman spectra of Co(III)TMPyP(4)Cl and Mn(III)TMPyP(4)Cl [where TMPyP(4) = tetrakis (4‐N‐methylpyridyl)porphyrin] demonstrate the formation of Ag(II)TMPyP(4) on the silver surface. The reaction is not photon assisted but is dependent on the sol activity and time. The effect of NaCl on the sol activity and the surface‐induced reaction was investigated. It was observed that the metal substitution reaction of Mn(III)TMPyP(4)Cl was more efficient than that of Co(III)TMPyP(4)Cl.

AB - The Surface‐enhanced Raman spectra of Co(III)TMPyP(4)Cl and Mn(III)TMPyP(4)Cl [where TMPyP(4) = tetrakis (4‐N‐methylpyridyl)porphyrin] demonstrate the formation of Ag(II)TMPyP(4) on the silver surface. The reaction is not photon assisted but is dependent on the sol activity and time. The effect of NaCl on the sol activity and the surface‐induced reaction was investigated. It was observed that the metal substitution reaction of Mn(III)TMPyP(4)Cl was more efficient than that of Co(III)TMPyP(4)Cl.

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DO - 10.1002/jrs.1250211006

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AN - SCOPUS:84988203480

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VL - 21

SP - 667

EP - 674

JO - Journal of Raman Spectroscopy

JF - Journal of Raman Spectroscopy

IS - 10

ER -

Surface‐induced substitution reaction on cobalt(III) and manganese(III) tetrakis (4‐N‐methylpyridyl)porphyrins probed by surface‐enhanced Raman spectroscopy

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