TY - JOUR
T1 - Subporphyrins with an axial B-C bond
AU - Saga, Shun
AU - Hayashi, Shin Ya
AU - Yoshida, Kouta
AU - Tsurumaki, Eiji
AU - Kim, Pyosang
AU - Sung, Young Mo
AU - Sung, Jooyoung
AU - Tanaka, Takayuki
AU - Kim, Dongho
AU - Osuka, Atsuhiro
PY - 2013/8/19
Y1 - 2013/8/19
N2 - Axial fabrications of subporphyrins have been conveniently accomplished by the reaction of B(methoxo)triphenylsubporphyrin with Grignard reagents such as aryl-, heteroaryl-, ferrocenyl-, β-styryl-, phenylethynyl-, and ethylmagnesium bromides. The axial groups thus introduced are not conjugated with the subporphyrin core. This situation leads to effective fluorescence quenching of subporphyrins when the axial group is strongly electron donating such as 4-dimethylaminophenyl and ferrocenyl groups.
AB - Axial fabrications of subporphyrins have been conveniently accomplished by the reaction of B(methoxo)triphenylsubporphyrin with Grignard reagents such as aryl-, heteroaryl-, ferrocenyl-, β-styryl-, phenylethynyl-, and ethylmagnesium bromides. The axial groups thus introduced are not conjugated with the subporphyrin core. This situation leads to effective fluorescence quenching of subporphyrins when the axial group is strongly electron donating such as 4-dimethylaminophenyl and ferrocenyl groups.
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U2 - 10.1002/chem.201302454
DO - 10.1002/chem.201302454
M3 - Article
C2 - 23857881
AN - SCOPUS:84882243242
SN - 0947-6539
VL - 19
SP - 11158
EP - 11161
JO - Chemistry - A European Journal
JF - Chemistry - A European Journal
IS - 34
ER -