Structural modulation of silicon nanowires by combining a high gas flow rate with metal catalysts

Dongjea Seo; Jaejun Lee; Sung Wook Kim; Ilsoo Kim; Jukwan Na; Min Ho Hong; Heon Jin Choi

doi:10.1186/s11671-015-0893-4

Structural modulation of silicon nanowires by combining a high gas flow rate with metal catalysts

Dongjea Seo, Jaejun Lee, Sung Wook Kim, Ilsoo Kim, Jukwan Na, Min Ho Hong, Heon Jin Choi

Department of Materials Science and Engineering

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

We grew silicon nanowires (SiNWs) by a vapor-liquid-solid (VLS) mechanism using metal catalysts of gold (Au), titanium (Ti), manganese (Mn), and iron (Fe) under a high flow rate of hydrogen (H₂). This combination of catalyst types and high gas flow rate revealed the potential for growing various SiNWs, including kinked SiNWs (with Au), ultra-thin SiNWs having diameters about 5 nm (with Ti), rough-surfaced SiNWs (with Mn), and ribbon-shaped SiNWs tens of microns in width (with Fe). The high flow rate of gas affects the VLS mechanism differently for each combination; for example, it induces an unstable solid-liquid interfaces (with Au), active etching of the catalyst (with Ti), sidewall deposition by a vapor-solid (VS) mechanism, and an asymmetric precipitation of Si in the catalyst (with Fe). Our combinatorial approach may provide a new path for the structural modulation of SiNWs via the VLS mechanism.

Original language	English
Article number	190
Journal	Nanoscale Research Letters
Volume	10
Issue number	1
DOIs	https://doi.org/10.1186/s11671-015-0893-4
Publication status	Published - 2015 Dec 22

Bibliographical note

Funding Information:
This research was supported by Nanomaterials Technology Development program (Green Nano Technology Development program) through the National Research Foundation of Korea (NRF) funded by the Ministry of Education Science and Technology (NRF-2014M3A7B4051580) and grant (NRF-2012R1A2A1A03010558) from the National Research Foundation (NRF) of Korea funded by the Ministry of Science, the Yonsei University-SNU collaborative Research Fund of 2014.

Publisher Copyright:
© 2015, Seo et al.; licensee Springer.

All Science Journal Classification (ASJC) codes

Materials Science(all)
Condensed Matter Physics

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10.1186/s11671-015-0893-4

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abstract = "We grew silicon nanowires (SiNWs) by a vapor-liquid-solid (VLS) mechanism using metal catalysts of gold (Au), titanium (Ti), manganese (Mn), and iron (Fe) under a high flow rate of hydrogen (H2). This combination of catalyst types and high gas flow rate revealed the potential for growing various SiNWs, including kinked SiNWs (with Au), ultra-thin SiNWs having diameters about 5 nm (with Ti), rough-surfaced SiNWs (with Mn), and ribbon-shaped SiNWs tens of microns in width (with Fe). The high flow rate of gas affects the VLS mechanism differently for each combination; for example, it induces an unstable solid-liquid interfaces (with Au), active etching of the catalyst (with Ti), sidewall deposition by a vapor-solid (VS) mechanism, and an asymmetric precipitation of Si in the catalyst (with Fe). Our combinatorial approach may provide a new path for the structural modulation of SiNWs via the VLS mechanism.",

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note = "Funding Information: This research was supported by Nanomaterials Technology Development program (Green Nano Technology Development program) through the National Research Foundation of Korea (NRF) funded by the Ministry of Education Science and Technology (NRF-2014M3A7B4051580) and grant (NRF-2012R1A2A1A03010558) from the National Research Foundation (NRF) of Korea funded by the Ministry of Science, the Yonsei University-SNU collaborative Research Fund of 2014. Publisher Copyright: {\textcopyright} 2015, Seo et al.; licensee Springer.",

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AU - Na, Jukwan

AU - Hong, Min Ho

AU - Choi, Heon Jin

N1 - Funding Information: This research was supported by Nanomaterials Technology Development program (Green Nano Technology Development program) through the National Research Foundation of Korea (NRF) funded by the Ministry of Education Science and Technology (NRF-2014M3A7B4051580) and grant (NRF-2012R1A2A1A03010558) from the National Research Foundation (NRF) of Korea funded by the Ministry of Science, the Yonsei University-SNU collaborative Research Fund of 2014. Publisher Copyright: © 2015, Seo et al.; licensee Springer.

PY - 2015/12/22

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N2 - We grew silicon nanowires (SiNWs) by a vapor-liquid-solid (VLS) mechanism using metal catalysts of gold (Au), titanium (Ti), manganese (Mn), and iron (Fe) under a high flow rate of hydrogen (H2). This combination of catalyst types and high gas flow rate revealed the potential for growing various SiNWs, including kinked SiNWs (with Au), ultra-thin SiNWs having diameters about 5 nm (with Ti), rough-surfaced SiNWs (with Mn), and ribbon-shaped SiNWs tens of microns in width (with Fe). The high flow rate of gas affects the VLS mechanism differently for each combination; for example, it induces an unstable solid-liquid interfaces (with Au), active etching of the catalyst (with Ti), sidewall deposition by a vapor-solid (VS) mechanism, and an asymmetric precipitation of Si in the catalyst (with Fe). Our combinatorial approach may provide a new path for the structural modulation of SiNWs via the VLS mechanism.

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Structural modulation of silicon nanowires by combining a high gas flow rate with metal catalysts

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