Structural and electronic characteristics induced by carbonization control of mesoporous carbon nanofibers

Ji Eun Im; Min Soo Son; Jing Li; Kyung Hwa Yoo; Yong Rok Kim

doi:10.1016/j.mseb.2014.04.001

Structural and electronic characteristics induced by carbonization control of mesoporous carbon nanofibers

Ji Eun Im, Min Soo Son, Jing Li, Kyung Hwa Yoo, Yong Rok Kim

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

Mesoporous carbon nanofibers (MCNFs) are fabricated at various carbonization temperatures. The carbonization temperature plays a key role in determining the structural characteristics and the electronic properties of MCNFs. The band gap energies of MCNFs are estimated to be 0.080, 0.036, and 0.014 eV at the carbonization temperatures of 600, 900, and 1200 °C, respectively. The MCNF carbonized at 1200 °C has the highest stacking height of graphene planes (L_c) and the largest number of graphene layers (L_c/d). Raman data show the intensity ratio of D to G peaks, which is related to the graphene size (L_a). L_a increases with increasing the carbonization temperature. In addition, as the carbonization temperature increases, the conductivity of MCNF increases due to larges values of L_c, L_a, and L_c/d.

Original language	English
Pages (from-to)	9-14
Number of pages	6
Journal	Materials Science and Engineering B: Solid-State Materials for Advanced Technology
Volume	187
DOIs	https://doi.org/10.1016/j.mseb.2014.04.001
Publication status	Published - 2014 Sept

Bibliographical note

Funding Information:
This work was supported by the National Research Foundation of Korea Grant funded by the Korean Government (No. 2012M3A9C6049729 ). Prof. K.-H.Y. work has been financially supported by Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education, Science and Technology (Grant No. 2011-0017486 ).

All Science Journal Classification (ASJC) codes

Materials Science(all)
Condensed Matter Physics
Mechanics of Materials
Mechanical Engineering

Access to Document

10.1016/j.mseb.2014.04.001

Cite this

@article{d622c5e77021418ab97957d632107392,

title = "Structural and electronic characteristics induced by carbonization control of mesoporous carbon nanofibers",

abstract = "Mesoporous carbon nanofibers (MCNFs) are fabricated at various carbonization temperatures. The carbonization temperature plays a key role in determining the structural characteristics and the electronic properties of MCNFs. The band gap energies of MCNFs are estimated to be 0.080, 0.036, and 0.014 eV at the carbonization temperatures of 600, 900, and 1200 °C, respectively. The MCNF carbonized at 1200 °C has the highest stacking height of graphene planes (Lc) and the largest number of graphene layers (Lc/d). Raman data show the intensity ratio of D to G peaks, which is related to the graphene size (La). La increases with increasing the carbonization temperature. In addition, as the carbonization temperature increases, the conductivity of MCNF increases due to larges values of Lc, La, and Lc/d.",

author = "Im, {Ji Eun} and Son, {Min Soo} and Jing Li and Yoo, {Kyung Hwa} and Kim, {Yong Rok}",

note = "Funding Information: This work was supported by the National Research Foundation of Korea Grant funded by the Korean Government (No. 2012M3A9C6049729 ). Prof. K.-H.Y. work has been financially supported by Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education, Science and Technology (Grant No. 2011-0017486 ). ",

year = "2014",

month = sep,

doi = "10.1016/j.mseb.2014.04.001",

language = "English",

volume = "187",

pages = "9--14",

journal = "Materials Science and Engineering B: Solid-State Materials for Advanced Technology",

issn = "0921-5107",

publisher = "Elsevier BV",

}

TY - JOUR

T1 - Structural and electronic characteristics induced by carbonization control of mesoporous carbon nanofibers

AU - Im, Ji Eun

AU - Son, Min Soo

AU - Li, Jing

AU - Yoo, Kyung Hwa

AU - Kim, Yong Rok

N1 - Funding Information: This work was supported by the National Research Foundation of Korea Grant funded by the Korean Government (No. 2012M3A9C6049729 ). Prof. K.-H.Y. work has been financially supported by Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education, Science and Technology (Grant No. 2011-0017486 ).

PY - 2014/9

Y1 - 2014/9

N2 - Mesoporous carbon nanofibers (MCNFs) are fabricated at various carbonization temperatures. The carbonization temperature plays a key role in determining the structural characteristics and the electronic properties of MCNFs. The band gap energies of MCNFs are estimated to be 0.080, 0.036, and 0.014 eV at the carbonization temperatures of 600, 900, and 1200 °C, respectively. The MCNF carbonized at 1200 °C has the highest stacking height of graphene planes (Lc) and the largest number of graphene layers (Lc/d). Raman data show the intensity ratio of D to G peaks, which is related to the graphene size (La). La increases with increasing the carbonization temperature. In addition, as the carbonization temperature increases, the conductivity of MCNF increases due to larges values of Lc, La, and Lc/d.

AB - Mesoporous carbon nanofibers (MCNFs) are fabricated at various carbonization temperatures. The carbonization temperature plays a key role in determining the structural characteristics and the electronic properties of MCNFs. The band gap energies of MCNFs are estimated to be 0.080, 0.036, and 0.014 eV at the carbonization temperatures of 600, 900, and 1200 °C, respectively. The MCNF carbonized at 1200 °C has the highest stacking height of graphene planes (Lc) and the largest number of graphene layers (Lc/d). Raman data show the intensity ratio of D to G peaks, which is related to the graphene size (La). La increases with increasing the carbonization temperature. In addition, as the carbonization temperature increases, the conductivity of MCNF increases due to larges values of Lc, La, and Lc/d.

UR - http://www.scopus.com/inward/record.url?scp=84900515700&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84900515700&partnerID=8YFLogxK

U2 - 10.1016/j.mseb.2014.04.001

DO - 10.1016/j.mseb.2014.04.001

M3 - Article

AN - SCOPUS:84900515700

SN - 0921-5107

VL - 187

SP - 9

EP - 14

JO - Materials Science and Engineering B: Solid-State Materials for Advanced Technology

JF - Materials Science and Engineering B: Solid-State Materials for Advanced Technology

ER -

Structural and electronic characteristics induced by carbonization control of mesoporous carbon nanofibers

Abstract

Bibliographical note

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this