Stereodivergent access to rocaglaol enabled by dual catalytic asymmetric allylation

Byungjun Kim; Sarah Yunmi Lee

doi:10.1016/j.checat.2022.06.011

Stereodivergent access to rocaglaol enabled by dual catalytic asymmetric allylation

Byungjun Kim, Sarah Yunmi Lee

Department of Chemistry

Research output: Contribution to journal › Comment/debate › peer-review

1 Citation (Scopus)

Abstract

In a recent issue of Chem, Liu and Feng et al. report a stereodivergent allylation of benzofuran-3(2H)-one catalyzed by two chiral metal catalysts, a phosphoramidite-Ir complex and an N,N′-dioxide-ligated Lewis acid, and its application to the selective total synthesis of eight stereoisomers of rocaglaol, one of the flavagline-family bioactive molecules.

Original language	English
Pages (from-to)	1526-1529
Number of pages	4
Journal	Chem Catalysis
Volume	2
Issue number	7
DOIs	https://doi.org/10.1016/j.checat.2022.06.011
Publication status	Published - 2022 Jul 21

Bibliographical note

Publisher Copyright:
© 2022 Elsevier Inc.

All Science Journal Classification (ASJC) codes

Chemistry (miscellaneous)
Physical and Theoretical Chemistry
Organic Chemistry

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10.1016/j.checat.2022.06.011

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abstract = "In a recent issue of Chem, Liu and Feng et al. report a stereodivergent allylation of benzofuran-3(2H)-one catalyzed by two chiral metal catalysts, a phosphoramidite-Ir complex and an N,N′-dioxide-ligated Lewis acid, and its application to the selective total synthesis of eight stereoisomers of rocaglaol, one of the flavagline-family bioactive molecules.",

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N2 - In a recent issue of Chem, Liu and Feng et al. report a stereodivergent allylation of benzofuran-3(2H)-one catalyzed by two chiral metal catalysts, a phosphoramidite-Ir complex and an N,N′-dioxide-ligated Lewis acid, and its application to the selective total synthesis of eight stereoisomers of rocaglaol, one of the flavagline-family bioactive molecules.

AB - In a recent issue of Chem, Liu and Feng et al. report a stereodivergent allylation of benzofuran-3(2H)-one catalyzed by two chiral metal catalysts, a phosphoramidite-Ir complex and an N,N′-dioxide-ligated Lewis acid, and its application to the selective total synthesis of eight stereoisomers of rocaglaol, one of the flavagline-family bioactive molecules.

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Stereodivergent access to rocaglaol enabled by dual catalytic asymmetric allylation

Abstract

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