TY - JOUR
T1 - Stannylene or metallastanna(IV)ocane
T2 - A matter of formalism
AU - Brendler, Erica
AU - Wächtler, Erik
AU - Heine, Thomas
AU - Zhechkov, Lyuben
AU - Langer, Thorsten
AU - Pöttgen, Rainer
AU - Hill, Anthony F.
AU - Wagler, Jörg
PY - 2011/5/9
Y1 - 2011/5/9
N2 - Pushmi-pullyu with palladium: Although created by Ïa donation from SnCl2 to a PdII complex, the Sn-Pd bonds in the compounds depicted exhibit formal Ïa donation in the opposite direction. Computational and spectroscopic data support stannylpalladium (Pd I-SnIII) and palladastanna(IV)ocane (Pd0 SnIV) descriptions over stannylene coordination.
AB - Pushmi-pullyu with palladium: Although created by Ïa donation from SnCl2 to a PdII complex, the Sn-Pd bonds in the compounds depicted exhibit formal Ïa donation in the opposite direction. Computational and spectroscopic data support stannylpalladium (Pd I-SnIII) and palladastanna(IV)ocane (Pd0 SnIV) descriptions over stannylene coordination.
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U2 - 10.1002/anie.201007967
DO - 10.1002/anie.201007967
M3 - Article
C2 - 21495131
AN - SCOPUS:79955660989
SN - 1433-7851
VL - 50
SP - 4696
EP - 4700
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
IS - 20
ER -