Single crystal growth of two-dimensional cyano-bridged coordination polymer of Co(H2O)2Ni(CN)4¢4H2O using trisodium citrate dihydrate

Alowasheeir Azhar; Mohamed Barakat Zakaria; Jeonghun Kim; Jongbeom Na; Yusuf Valentino Kaneti; Amanullah Fatehmulla; Abdullah M. Aldhafiri; W. Aslam Farooq; Yoshio Bando; Yusuke Yamauchi; Jianjian Lin

doi:10.1246/bcsj.20190054

Single crystal growth of two-dimensional cyano-bridged coordination polymer of Co(H₂O)₂Ni(CN)₄¢4H₂O using trisodium citrate dihydrate

Alowasheeir Azhar, Mohamed Barakat Zakaria, Jeonghun Kim, Jongbeom Na, Yusuf Valentino Kaneti, Amanullah Fatehmulla, Abdullah M. Aldhafiri, W. Aslam Farooq, Yoshio Bando, Yusuke Yamauchi, Jianjian Lin

Department of Chemical and Biomolecular Engineering

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

Single crystal Co(H₂O)₂Ni(CN)₄¢4H₂O has been successfully synthesized by a slow diffusion method using trisodium citrate dihydrate for controlling the nucleation rate and the crystal growth. The single crystal X-ray diffraction results show the obtained crystals with a two-dimensional orthorhombic unit cell, assembled from cationic Co ions and anionic [Ni(CN)₄]²¹ units connected by bridging cyanide groups.

Original language	English
Pages (from-to)	1263-1267
Number of pages	5
Journal	Bulletin of the Chemical Society of Japan
Volume	92
Issue number	7
DOIs	https://doi.org/10.1246/bcsj.20190054
Publication status	Published - 2019

Bibliographical note

Funding Information:
A.A. thanks the Custodian of The Two Holy Mosques’ overseas scholarship program in the Kingdom of Saudi Arabia for financial support. The authors extend their appreciation to the International Scientific Partnership Program (ISPP) at King Saud University (KSU) for funding this research work through ISPP-66. The project was supported by the National Natural Science Foundation of China (NSFC) (61604070) and the National Natural Science Foundation of Jiangsu Province (BK20161000). This work was performed in part at the Queensland node of the Australian National Fabrication Facility, a company established under the National Collaborative Research Infrastructure Strategy to provide nano-and micro-fabrication facilities for Australia’s researchers.

Publisher Copyright:
© 2019 The Chemical Society of Japan

All Science Journal Classification (ASJC) codes

Chemistry(all)

Access to Document

10.1246/bcsj.20190054

Cite this

Azhar, A., Zakaria, M. B., Kim, J., Na, J., Kaneti, Y. V., Fatehmulla, A., Aldhafiri, A. M., Aslam Farooq, W., Bando, Y., Yamauchi, Y., & Lin, J. (2019). Single crystal growth of two-dimensional cyano-bridged coordination polymer of Co(H₂O)₂Ni(CN)₄¢4H₂O using trisodium citrate dihydrate. Bulletin of the Chemical Society of Japan, 92(7), 1263-1267. https://doi.org/10.1246/bcsj.20190054

@article{420be3dae3d64b5ab691add91963dd39,

title = "Single crystal growth of two-dimensional cyano-bridged coordination polymer of Co(H2O)2Ni(CN)4¢4H2O using trisodium citrate dihydrate",

abstract = "Single crystal Co(H2O)2Ni(CN)4¢4H2O has been successfully synthesized by a slow diffusion method using trisodium citrate dihydrate for controlling the nucleation rate and the crystal growth. The single crystal X-ray diffraction results show the obtained crystals with a two-dimensional orthorhombic unit cell, assembled from cationic Co ions and anionic [Ni(CN)4]21 units connected by bridging cyanide groups.",

author = "Alowasheeir Azhar and Zakaria, {Mohamed Barakat} and Jeonghun Kim and Jongbeom Na and Kaneti, {Yusuf Valentino} and Amanullah Fatehmulla and Aldhafiri, {Abdullah M.} and {Aslam Farooq}, W. and Yoshio Bando and Yusuke Yamauchi and Jianjian Lin",

note = "Funding Information: A.A. thanks the Custodian of The Two Holy Mosques{\textquoteright} overseas scholarship program in the Kingdom of Saudi Arabia for financial support. The authors extend their appreciation to the International Scientific Partnership Program (ISPP) at King Saud University (KSU) for funding this research work through ISPP-66. The project was supported by the National Natural Science Foundation of China (NSFC) (61604070) and the National Natural Science Foundation of Jiangsu Province (BK20161000). This work was performed in part at the Queensland node of the Australian National Fabrication Facility, a company established under the National Collaborative Research Infrastructure Strategy to provide nano-and micro-fabrication facilities for Australia{\textquoteright}s researchers. Publisher Copyright: {\textcopyright} 2019 The Chemical Society of Japan",

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Azhar, A, Zakaria, MB, Kim, J, Na, J, Kaneti, YV, Fatehmulla, A, Aldhafiri, AM, Aslam Farooq, W, Bando, Y, Yamauchi, Y & Lin, J 2019, 'Single crystal growth of two-dimensional cyano-bridged coordination polymer of Co(H₂O)₂Ni(CN)₄¢4H₂O using trisodium citrate dihydrate', Bulletin of the Chemical Society of Japan, vol. 92, no. 7, pp. 1263-1267. https://doi.org/10.1246/bcsj.20190054

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AU - Azhar, Alowasheeir

AU - Zakaria, Mohamed Barakat

AU - Kim, Jeonghun

AU - Na, Jongbeom

AU - Kaneti, Yusuf Valentino

AU - Fatehmulla, Amanullah

AU - Aldhafiri, Abdullah M.

AU - Aslam Farooq, W.

AU - Bando, Yoshio

AU - Yamauchi, Yusuke

AU - Lin, Jianjian

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PY - 2019

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N2 - Single crystal Co(H2O)2Ni(CN)4¢4H2O has been successfully synthesized by a slow diffusion method using trisodium citrate dihydrate for controlling the nucleation rate and the crystal growth. The single crystal X-ray diffraction results show the obtained crystals with a two-dimensional orthorhombic unit cell, assembled from cationic Co ions and anionic [Ni(CN)4]21 units connected by bridging cyanide groups.

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