Single Atom Selenium Substitution-Mediated P-Type Doping in Polythiophenes toward High-Performance Organic Electronics and Thermoelectrics

Chen Chen, Ian E. Jacobs, Cameron Jellett, Xuechen Jiao, James F. Ponder, Boseok Kang, Seon Baek Lee, Yuxuan Huang, Lu Zhang, Martin Statz, Yuanhui Sun, Yue Lin, Keehoon Kang, Xiaojian She, Yuanyuan Hu, Tao Zhang, Lang Jiang, Christopher R. McNeill, Iain McCulloch, Henning Sirringhaus

Research output: Contribution to journalArticlepeer-review

3 Citations (Scopus)


Heavy heteroatom substitution of the backbone is an effective strategy to improve molecular packing and charge delocalization in polymer semiconductors. Such a backbone modification also facilitates oxidative doping as a result of reduced ionization potential (IP). Here, the effect of single-atom selenium substitution on doping and charge transport properties of a class of polythiophene copolymers is explored. The room temperature (RT) conductivities of the doped polymers are significantly enhanced by the selenium substitution for both molecular doping and ion exchange doping. The enhanced conduction is rationalized by the better crystallinity of the selenium-containing system, which can be reinforced by a chain-extended ribbon-phase morphology induced by thermal annealing, which is robust toward doping. The resulting increase in the charge delocalization of the doped selenium-containing system is evidenced by temperature-dependent conductivities. In ion exchange doped films the maximum conductivity of ≈700 S cm−1 and a high thermoelectric (TE) power factor (PF) of 46.5 μW m−1 K−2 is achieved for the doped selenophene polymer and signatures of a metal-insulator (M–I) transition are observed that are characteristics for heterogeneous conduction systems. The results show that single-atom selenium substitution is an effective molecular design approach for improving the charge transport and TE properties of conjugated polymers.

Original languageEnglish
Article number2200053
JournalAdvanced Electronic Materials
Issue number11
Publication statusPublished - 2022 Nov

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© 2022 The Authors. Advanced Electronic Materials published by Wiley-VCH GmbH.

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials


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