Sequential energy transfer followed by electron transfer in a BODIPY-bisstyrylBODIPY bound to C60 triad: Via a 'two-point' binding strategy

Shuai Shao; Michael B. Thomas; Kyu Hyung Park; Zoe Mahaffey; Dongho Kim; Francis D'Souza

doi:10.1039/c7cc08063h

Sequential energy transfer followed by electron transfer in a BODIPY-bisstyrylBODIPY bound to C₆₀ triad: Via a 'two-point' binding strategy

Shuai Shao, Michael B. Thomas, Kyu Hyung Park, Zoe Mahaffey, Dongho Kim, Francis D'Souza

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

26 Citations (Scopus)

Abstract

Excitation transfer from ¹BODIPY∗ to bisstyrylBODIPY followed by electron transfer to C₆₀ leading to a charge separated state of appreciable lifetime in a supramolecularly assembled triad is demonstrated, as a mimic of the photosynthetic 'antenna-reaction centre'.

Original language	English
Pages (from-to)	54-57
Number of pages	4
Journal	Chemical Communications
Volume	54
Issue number	1
DOIs	https://doi.org/10.1039/c7cc08063h
Publication status	Published - 2017

Bibliographical note

Funding Information:
The authors are thankful to the National Science Foundation (Grant No. 1401188) and the National Research Foundation of Korea (NRF) funded by the Korea government (MEST) (2016R1E1A1A01943379) for support of this work. We thank Dr Guido Verbeck and the Laboratory for Imaging Mass Spectrometry at the University of North Texas for MALDI-Orbitrap Mass Spectrometry data.

Publisher Copyright:
© 2017 The Royal Society of Chemistry.

All Science Journal Classification (ASJC) codes

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

Access to Document

10.1039/c7cc08063h

Cite this

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title = "Sequential energy transfer followed by electron transfer in a BODIPY-bisstyrylBODIPY bound to C60 triad: Via a 'two-point' binding strategy",

abstract = "Excitation transfer from 1BODIPY∗ to bisstyrylBODIPY followed by electron transfer to C60 leading to a charge separated state of appreciable lifetime in a supramolecularly assembled triad is demonstrated, as a mimic of the photosynthetic 'antenna-reaction centre'.",

author = "Shuai Shao and Thomas, {Michael B.} and Park, {Kyu Hyung} and Zoe Mahaffey and Dongho Kim and Francis D'Souza",

note = "Funding Information: The authors are thankful to the National Science Foundation (Grant No. 1401188) and the National Research Foundation of Korea (NRF) funded by the Korea government (MEST) (2016R1E1A1A01943379) for support of this work. We thank Dr Guido Verbeck and the Laboratory for Imaging Mass Spectrometry at the University of North Texas for MALDI-Orbitrap Mass Spectrometry data. Publisher Copyright: {\textcopyright} 2017 The Royal Society of Chemistry.",

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AU - Shao, Shuai

AU - Thomas, Michael B.

AU - Park, Kyu Hyung

AU - Mahaffey, Zoe

AU - Kim, Dongho

AU - D'Souza, Francis

N1 - Funding Information: The authors are thankful to the National Science Foundation (Grant No. 1401188) and the National Research Foundation of Korea (NRF) funded by the Korea government (MEST) (2016R1E1A1A01943379) for support of this work. We thank Dr Guido Verbeck and the Laboratory for Imaging Mass Spectrometry at the University of North Texas for MALDI-Orbitrap Mass Spectrometry data. Publisher Copyright: © 2017 The Royal Society of Chemistry.

PY - 2017

Y1 - 2017

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AB - Excitation transfer from 1BODIPY∗ to bisstyrylBODIPY followed by electron transfer to C60 leading to a charge separated state of appreciable lifetime in a supramolecularly assembled triad is demonstrated, as a mimic of the photosynthetic 'antenna-reaction centre'.

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