Self-Assembly of Interlocked Supramolecular Dendrimers

Kyu Sung Jeong; Eun Jin Park

doi:10.1021/jo035798u

Self-Assembly of Interlocked Supramolecular Dendrimers

Kyu Sung Jeong, Eun Jin Park

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

17 Citations (Scopus)

Abstract

Interlocked supramolecular dendrimers were spontaneously self-assembled from molecular components, metallocycles, and dumbbells bearing benzyl ether repeating units. Here, the metallocycles were in situ self-assembled from L-shaped ligands with dendritic branches, 2,3-dimethyl-2-butene and osmium tetraoxide. The supramolecular dendrimers were stabilized by hydrogen-bonding interactions between the pyridine-2,6-dicarboxamide unit in the metallocycle and the adipamide unit in the dumbbell.

Original language	English
Pages (from-to)	2618-2621
Number of pages	4
Journal	Journal of Organic Chemistry
Volume	69
Issue number	7
DOIs	https://doi.org/10.1021/jo035798u
Publication status	Published - 2004 Apr 2

All Science Journal Classification (ASJC) codes

Organic Chemistry

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10.1021/jo035798u

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AB - Interlocked supramolecular dendrimers were spontaneously self-assembled from molecular components, metallocycles, and dumbbells bearing benzyl ether repeating units. Here, the metallocycles were in situ self-assembled from L-shaped ligands with dendritic branches, 2,3-dimethyl-2-butene and osmium tetraoxide. The supramolecular dendrimers were stabilized by hydrogen-bonding interactions between the pyridine-2,6-dicarboxamide unit in the metallocycle and the adipamide unit in the dumbbell.

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Self-Assembly of Interlocked Supramolecular Dendrimers

Abstract

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