Rh(I)-catalyzed O-silylation of alcohol with vinylsilane

Jung Woo Park; Hoon Jo Chang; Chul Ho Jun

doi:10.2106/JBJS.E.00762

Rh(I)-catalyzed O-silylation of alcohol with vinylsilane

Jung Woo Park, Hoon Jo Chang, Chul Ho Jun

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

21 Citations (Scopus)

Abstract

Silyl ethers can be produced from alcohols and vinylsilanes under a rhodium(I) catalyst. The reaction is believed to proceed through an O-H bond cleavage of alcohol by rhodium(I) complex and a subsequent hydride insertion into vinylsilane followed by β-silyl elimination of the resulting β-silylethyl rhodium(III) complex.

Original language	English
Pages (from-to)	771-775
Number of pages	5
Journal	Synlett
Issue number	5
DOIs	https://doi.org/10.2106/JBJS.E.00762
Publication status	Published - 2006 Mar 17

All Science Journal Classification (ASJC) codes

Organic Chemistry

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10.2106/JBJS.E.00762

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title = "Rh(I)-catalyzed O-silylation of alcohol with vinylsilane",

abstract = "Silyl ethers can be produced from alcohols and vinylsilanes under a rhodium(I) catalyst. The reaction is believed to proceed through an O-H bond cleavage of alcohol by rhodium(I) complex and a subsequent hydride insertion into vinylsilane followed by β-silyl elimination of the resulting β-silylethyl rhodium(III) complex.",

author = "Park, {Jung Woo} and Chang, {Hoon Jo} and Jun, {Chul Ho}",

year = "2006",

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AU - Chang, Hoon Jo

AU - Jun, Chul Ho

PY - 2006/3/17

Y1 - 2006/3/17

N2 - Silyl ethers can be produced from alcohols and vinylsilanes under a rhodium(I) catalyst. The reaction is believed to proceed through an O-H bond cleavage of alcohol by rhodium(I) complex and a subsequent hydride insertion into vinylsilane followed by β-silyl elimination of the resulting β-silylethyl rhodium(III) complex.

AB - Silyl ethers can be produced from alcohols and vinylsilanes under a rhodium(I) catalyst. The reaction is believed to proceed through an O-H bond cleavage of alcohol by rhodium(I) complex and a subsequent hydride insertion into vinylsilane followed by β-silyl elimination of the resulting β-silylethyl rhodium(III) complex.

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Rh(I)-catalyzed O-silylation of alcohol with vinylsilane

Abstract

All Science Journal Classification (ASJC) codes

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