Resonance raman spectroscopic study of fused multiporphyrin linear arrays

Dae Hong Jeong; Sung Moon Jang; In Wook Hwang; Dongho Kim; Yoichi Matsuzaki; Kazuyoshi Tanaka; Akihiko Tsuda; Takeshi Nakamura; Atsuhiro Osuka

doi:10.1063/1.1596854

Resonance raman spectroscopic study of fused multiporphyrin linear arrays

Dae Hong Jeong, Sung Moon Jang, In Wook Hwang, Dongho Kim, Yoichi Matsuzaki, Kazuyoshi Tanaka, Akihiko Tsuda, Takeshi Nakamura, Atsuhiro Osuka

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

The lowest electronic transitions of Tn are continuously redshifted to the IR region due to much enhanced π-electron delocalization throughout the entire fused porphyrin array. This unique feature provides a promising possibility for the application of Tn as electric wires in molecular electronics. To investigate the electronic transition in relation to the molecular structures of Tn, the resonance Raman spectra of Tn are recorded by changing the photoexcitation wavelength.

Original language	English
Pages (from-to)	5237-5252
Number of pages	16
Journal	Journal of Chemical Physics
Volume	119
Issue number	10
DOIs	https://doi.org/10.1063/1.1596854
Publication status	Published - 2003 Sept 8

All Science Journal Classification (ASJC) codes

Physics and Astronomy(all)
Physical and Theoretical Chemistry

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10.1063/1.1596854

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author = "Jeong, {Dae Hong} and Jang, {Sung Moon} and Hwang, {In Wook} and Dongho Kim and Yoichi Matsuzaki and Kazuyoshi Tanaka and Akihiko Tsuda and Takeshi Nakamura and Atsuhiro Osuka",

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AU - Jeong, Dae Hong

AU - Jang, Sung Moon

AU - Hwang, In Wook

AU - Kim, Dongho

AU - Matsuzaki, Yoichi

AU - Tanaka, Kazuyoshi

AU - Tsuda, Akihiko

AU - Nakamura, Takeshi

AU - Osuka, Atsuhiro

PY - 2003/9/8

Y1 - 2003/9/8

N2 - The lowest electronic transitions of Tn are continuously redshifted to the IR region due to much enhanced π-electron delocalization throughout the entire fused porphyrin array. This unique feature provides a promising possibility for the application of Tn as electric wires in molecular electronics. To investigate the electronic transition in relation to the molecular structures of Tn, the resonance Raman spectra of Tn are recorded by changing the photoexcitation wavelength.

AB - The lowest electronic transitions of Tn are continuously redshifted to the IR region due to much enhanced π-electron delocalization throughout the entire fused porphyrin array. This unique feature provides a promising possibility for the application of Tn as electric wires in molecular electronics. To investigate the electronic transition in relation to the molecular structures of Tn, the resonance Raman spectra of Tn are recorded by changing the photoexcitation wavelength.

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JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

IS - 10

ER -

Resonance raman spectroscopic study of fused multiporphyrin linear arrays

Abstract

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