Reducing emission of carcinogenic by-products in the production of thermally reduced graphene oxide

Ondřej Jankovský, Michal Lojka, Michal Nováček, Jan Luxa, David Sedmidubský, Martin Pumera, Jiří Kosina, Zdeněk Sofer

Research output: Contribution to journalArticlepeer-review

10 Citations (Scopus)


In the last decade, researchers have been trying to find out a simple method for large scale fabrication of high-quality graphene. A typical method for the fabrication of gram quantities of graphene materials is the oxidation of graphite to graphite oxide and consequent thermal reduction and exfoliation to reduced graphene oxide at T = ∼1000 °C. Here we show that highly reduced graphene oxide can be prepared at lower temperatures than 1000 °C while keeping the properties of graphene suitable for various electrochemical applications. The high temperature exfoliation of graphite oxide typically leads to the formation of a large amount of highly toxic volatile organic hydrocarbons such as benzene and its derivatives. The amount of volatile aromatic hydrocarbons can be reduced using low temperature exfoliation procedures that we present here. The application of a lower exfoliation temperature is highly beneficial as it also significantly reduces the etching of the graphene skeleton and the formation of toxic aromatic hydrocarbons. The effect of thermal exfoliation was investigated in detail for the temperature range of 400 °C up to 1000 °C under hydrogen as well as nitrogen atmospheres. Our findings show the route for the preparation of thermally reduced graphene oxide suitable for various electrochemical applications without the formation of toxic hydrocarbons as reaction byproducts. These findings are of high importance for the industrial scale production of thermally reduced graphene oxide.

Original languageEnglish
Pages (from-to)6618-6629
Number of pages12
JournalGreen Chemistry
Issue number24
Publication statusPublished - 2016

Bibliographical note

Funding Information:
The project was supported by the Czech Science Foundation (GACR No. 15-09001S and 16-05167S) and financial support was received from specific university research (MSMT No. 20-SVV/2016). M. P. acknowledges a Tier 2 grant (MOE2013-T2-1-056; ARC 35/13) from the Ministry of Education, Singapore.

Publisher Copyright:
© 2016 The Royal Society of Chemistry.

All Science Journal Classification (ASJC) codes

  • Environmental Chemistry
  • Pollution


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