TY - JOUR
T1 - Redox-active organometallic Ir complexes containing biphenyl-2,2′- diyl
AU - Lu, Zheng
AU - Jun, Chul Ho
AU - De Gala, Susan R.
AU - Sigalas, Michel
AU - Eisenstein, Odile
AU - Crabtree, Robert H.
PY - 1993
Y1 - 1993
N2 - The redox-active complexes [Ir(PPh3)2(biph)Cl] 3 and [Ir(PMe3)3(biph)Cl] 6 contain biphenyl-2,2-diyl (biph), the organometallic analogue of bipy; 3 shows an unexpected five-coordinate structure lying between T and Y geometry and oxidation of 6 by NOBF4 gives [Ir(PMe3)3(biphBF)Cl]+ (8)+, an unprecedented IrIV boryl complex.
AB - The redox-active complexes [Ir(PPh3)2(biph)Cl] 3 and [Ir(PMe3)3(biph)Cl] 6 contain biphenyl-2,2-diyl (biph), the organometallic analogue of bipy; 3 shows an unexpected five-coordinate structure lying between T and Y geometry and oxidation of 6 by NOBF4 gives [Ir(PMe3)3(biphBF)Cl]+ (8)+, an unprecedented IrIV boryl complex.
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U2 - 10.1039/C39930001877
DO - 10.1039/C39930001877
M3 - Article
AN - SCOPUS:33745165541
SN - 0022-4936
SP - 1877
EP - 1880
JO - Journal of the Chemical Society, Chemical Communications
JF - Journal of the Chemical Society, Chemical Communications
IS - 24
ER -