Radical mono- and dideoxygenations with the triethylsilane + benzoyl peroxide system.

Derek H.R. Barton; Doo Ok Jang; Joseph Cs Jaszberenyi

doi:10.1016/0040-4039(91)80472-I

Radical mono- and dideoxygenations with the triethylsilane + benzoyl peroxide system.

Derek H.R. Barton, Doo Ok Jang, Joseph Cs Jaszberenyi

Chemistry and Medical Chemistry

Research output: Contribution to journal › Article › peer-review

57 Citations (Scopus)

Abstract

Thionocarbonates and xanthates of primary and secondary alcohols, as well as dixanthates of vic-diols can easily be deoxygenated to the corresponding hydrocarbons or olefins with triethylsilane and benzoyl peroxide in high-yielding radical reactions.

Original language	English
Pages (from-to)	7187-7190
Number of pages	4
Journal	Tetrahedron Letters
Volume	32
Issue number	49
DOIs	https://doi.org/10.1016/0040-4039(91)80472-I
Publication status	Published - 1991 Dec 2

Bibliographical note

Funding Information:
and the Schering-Plough Corporation for financial support.

All Science Journal Classification (ASJC) codes

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/0040-4039(91)80472-I

Cite this

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title = "Radical mono- and dideoxygenations with the triethylsilane + benzoyl peroxide system.",

abstract = "Thionocarbonates and xanthates of primary and secondary alcohols, as well as dixanthates of vic-diols can easily be deoxygenated to the corresponding hydrocarbons or olefins with triethylsilane and benzoyl peroxide in high-yielding radical reactions.",

author = "Barton, {Derek H.R.} and Jang, {Doo Ok} and Jaszberenyi, {Joseph Cs}",

note = "Funding Information: and the Schering-Plough Corporation for financial support.",

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AU - Jang, Doo Ok

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N1 - Funding Information: and the Schering-Plough Corporation for financial support.

PY - 1991/12/2

Y1 - 1991/12/2

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AB - Thionocarbonates and xanthates of primary and secondary alcohols, as well as dixanthates of vic-diols can easily be deoxygenated to the corresponding hydrocarbons or olefins with triethylsilane and benzoyl peroxide in high-yielding radical reactions.

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Radical mono- and dideoxygenations with the triethylsilane + benzoyl peroxide system.

Abstract

Bibliographical note

All Science Journal Classification (ASJC) codes

Access to Document

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