Radical deoxygenation of tertiary alcohols via trifluoroacetates

Joong Gon Kim; Dae Hyan Cho; Doo Ok Jang

doi:10.1016/j.tetlet.2004.02.109

Radical deoxygenation of tertiary alcohols via trifluoroacetates

Joong Gon Kim, Dae Hyan Cho, Doo Ok Jang

Chemistry and Medical Chemistry

Research output: Contribution to journal › Article › peer-review

13 Citations (Scopus)

Abstract

Trifluoroacetates of tertiary alcohols undergo deoxygenation by Ph ₂SiH₂ in the presence of (^tBuO)₂ in excellent yields of the deoxy products without affecting the stereochemistry at β-carbon.

Original language	English
Pages (from-to)	3031-3033
Number of pages	3
Journal	Tetrahedron Letters
Volume	45
Issue number	15
DOIs	https://doi.org/10.1016/j.tetlet.2004.02.109
Publication status	Published - 2004 Apr 5

Bibliographical note

Funding Information:
This work was supported by Korea Research Foundation Grant (KRF-2002-015-CP0214).

All Science Journal Classification (ASJC) codes

Biochemistry
Drug Discovery
Organic Chemistry

Access to Document

10.1016/j.tetlet.2004.02.109

Cite this

@article{81dfab72358d4df9bef8e6c70426f2dd,

title = "Radical deoxygenation of tertiary alcohols via trifluoroacetates",

abstract = "Trifluoroacetates of tertiary alcohols undergo deoxygenation by Ph 2SiH2 in the presence of (tBuO)2 in excellent yields of the deoxy products without affecting the stereochemistry at β-carbon.",

author = "Kim, {Joong Gon} and Cho, {Dae Hyan} and Jang, {Doo Ok}",

note = "Funding Information: This work was supported by Korea Research Foundation Grant (KRF-2002-015-CP0214). ",

year = "2004",

month = apr,

day = "5",

doi = "10.1016/j.tetlet.2004.02.109",

language = "English",

volume = "45",

pages = "3031--3033",

journal = "Tetrahedron Letters",

issn = "0040-4039",

publisher = "Elsevier Limited",

number = "15",

}

TY - JOUR

T1 - Radical deoxygenation of tertiary alcohols via trifluoroacetates

AU - Kim, Joong Gon

AU - Cho, Dae Hyan

AU - Jang, Doo Ok

N1 - Funding Information: This work was supported by Korea Research Foundation Grant (KRF-2002-015-CP0214).

PY - 2004/4/5

Y1 - 2004/4/5

N2 - Trifluoroacetates of tertiary alcohols undergo deoxygenation by Ph 2SiH2 in the presence of (tBuO)2 in excellent yields of the deoxy products without affecting the stereochemistry at β-carbon.

AB - Trifluoroacetates of tertiary alcohols undergo deoxygenation by Ph 2SiH2 in the presence of (tBuO)2 in excellent yields of the deoxy products without affecting the stereochemistry at β-carbon.

UR - http://www.scopus.com/inward/record.url?scp=1642387676&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=1642387676&partnerID=8YFLogxK

U2 - 10.1016/j.tetlet.2004.02.109

DO - 10.1016/j.tetlet.2004.02.109

M3 - Article

AN - SCOPUS:1642387676

SN - 0040-4039

VL - 45

SP - 3031

EP - 3033

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 15

ER -

Radical deoxygenation of tertiary alcohols via trifluoroacetates

Abstract

Bibliographical note

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this