PSS resin-fortified polythiophene nanoparticles for highly transparent conducting films

Sun Jong Lee; Ki Nam Oh; Jung Min Lee; Jung Hyun Kim; In Woo Cheong

doi:10.1166/jnn.2010.2951

PSS resin-fortified polythiophene nanoparticles for highly transparent conducting films

Sun Jong Lee, Ki Nam Oh, Jung Min Lee, Jung Hyun Kim, In Woo Cheong

Department of Chemical and Biomolecular Engineering

Research output: Contribution to journal › Article › peer-review

Abstract

Polythiophene/poly(sodium 4-styrene sulfonate) (PT/PSS) composite nanoparticles having different particle size were prepared by Fe ³⁺-catalyzed oxidative polymerization in aqueous medium. This facile method includes a FeCI ₃/H ₂0 ₂ (catalyst/oxidant) combination system, which guarantees a high conversion (more than 95%) of thiophene monomers in various concentration of poly(styrene sulfonate) (PSS) with only a trace of FeCI ₃. Particle size of PT/PSS composite nanoparticles decreased from 134 nm to 26 nm as the concentration of PSS and H ₂0 ₂ increased, and which was confirmed by SEM and CHDF analyses. The poly(ethylene terephthalate) (PET) film coated with PT/PSS was transparent and showed a high conductivity in a dried state. The sheet resistivity decreased as the ratio of PT to PSS increased. Photoluminescence property of the PT/PSS composite nanoparticles was also investigated.

Original language	English
Pages (from-to)	6944-6947
Number of pages	4
Journal	Journal of Nanoscience and Nanotechnology
Volume	10
Issue number	10
DOIs	https://doi.org/10.1166/jnn.2010.2951
Publication status	Published - 2010 Oct

All Science Journal Classification (ASJC) codes

Bioengineering
Chemistry(all)
Biomedical Engineering
Materials Science(all)
Condensed Matter Physics

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10.1166/jnn.2010.2951

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title = "PSS resin-fortified polythiophene nanoparticles for highly transparent conducting films",

abstract = "Polythiophene/poly(sodium 4-styrene sulfonate) (PT/PSS) composite nanoparticles having different particle size were prepared by Fe 3+-catalyzed oxidative polymerization in aqueous medium. This facile method includes a FeCI 3/H 20 2 (catalyst/oxidant) combination system, which guarantees a high conversion (more than 95%) of thiophene monomers in various concentration of poly(styrene sulfonate) (PSS) with only a trace of FeCI 3. Particle size of PT/PSS composite nanoparticles decreased from 134 nm to 26 nm as the concentration of PSS and H 20 2 increased, and which was confirmed by SEM and CHDF analyses. The poly(ethylene terephthalate) (PET) film coated with PT/PSS was transparent and showed a high conductivity in a dried state. The sheet resistivity decreased as the ratio of PT to PSS increased. Photoluminescence property of the PT/PSS composite nanoparticles was also investigated.",

author = "Lee, {Sun Jong} and Oh, {Ki Nam} and Lee, {Jung Min} and Kim, {Jung Hyun} and Cheong, {In Woo}",

year = "2010",

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doi = "10.1166/jnn.2010.2951",

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T1 - PSS resin-fortified polythiophene nanoparticles for highly transparent conducting films

AU - Lee, Sun Jong

AU - Oh, Ki Nam

AU - Lee, Jung Min

AU - Kim, Jung Hyun

AU - Cheong, In Woo

PY - 2010/10

Y1 - 2010/10

N2 - Polythiophene/poly(sodium 4-styrene sulfonate) (PT/PSS) composite nanoparticles having different particle size were prepared by Fe 3+-catalyzed oxidative polymerization in aqueous medium. This facile method includes a FeCI 3/H 20 2 (catalyst/oxidant) combination system, which guarantees a high conversion (more than 95%) of thiophene monomers in various concentration of poly(styrene sulfonate) (PSS) with only a trace of FeCI 3. Particle size of PT/PSS composite nanoparticles decreased from 134 nm to 26 nm as the concentration of PSS and H 20 2 increased, and which was confirmed by SEM and CHDF analyses. The poly(ethylene terephthalate) (PET) film coated with PT/PSS was transparent and showed a high conductivity in a dried state. The sheet resistivity decreased as the ratio of PT to PSS increased. Photoluminescence property of the PT/PSS composite nanoparticles was also investigated.

AB - Polythiophene/poly(sodium 4-styrene sulfonate) (PT/PSS) composite nanoparticles having different particle size were prepared by Fe 3+-catalyzed oxidative polymerization in aqueous medium. This facile method includes a FeCI 3/H 20 2 (catalyst/oxidant) combination system, which guarantees a high conversion (more than 95%) of thiophene monomers in various concentration of poly(styrene sulfonate) (PSS) with only a trace of FeCI 3. Particle size of PT/PSS composite nanoparticles decreased from 134 nm to 26 nm as the concentration of PSS and H 20 2 increased, and which was confirmed by SEM and CHDF analyses. The poly(ethylene terephthalate) (PET) film coated with PT/PSS was transparent and showed a high conductivity in a dried state. The sheet resistivity decreased as the ratio of PT to PSS increased. Photoluminescence property of the PT/PSS composite nanoparticles was also investigated.

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PSS resin-fortified polythiophene nanoparticles for highly transparent conducting films

Abstract

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