TY - JOUR
T1 - Protonation-triggered conformational changes to Möbius aromatic [32]heptaphyrins(1.1.1.1.1.1.1)
AU - Saito, Shohei
AU - Shin, Jae Yoon
AU - Lim, Jong Min
AU - Kim, Kil Suk
AU - Kim, Dongho
AU - Osuka, Atsuhiro
PY - 2008/12/1
Y1 - 2008/12/1
N2 - Switching Aromaticity: Conformations of [32]heptaphyrins (1.1.1.1.1.1.1) are dependent upon meso-aryl substituents, solvents, temperature, and protonation. Particularly, protonation of meso-pentafluorophenyl-substituted [32]heptaphyrin triggers conformational changes to form twisted aromatic Möbius structures (see picture), even at room temperature. (Figure Presented).
AB - Switching Aromaticity: Conformations of [32]heptaphyrins (1.1.1.1.1.1.1) are dependent upon meso-aryl substituents, solvents, temperature, and protonation. Particularly, protonation of meso-pentafluorophenyl-substituted [32]heptaphyrin triggers conformational changes to form twisted aromatic Möbius structures (see picture), even at room temperature. (Figure Presented).
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U2 - 10.1002/anie.200804457
DO - 10.1002/anie.200804457
M3 - Article
C2 - 19021175
AN - SCOPUS:57049099788
SN - 1433-7851
VL - 47
SP - 9657
EP - 9660
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
IS - 50
ER -