Probing Reaction Dynamics of Transition-Metal Complexes in Solution via Time-Resolved Soft X-ray Spectroscopy

Nils Huse; Tae Kyu Kim; Munira Khalil; Lindsey Jamula; James K. McCusker; Robert W. Schoenlein

doi:10.1007/978-3-540-95946-5_41

Probing Reaction Dynamics of Transition-Metal Complexes in Solution via Time-Resolved Soft X-ray Spectroscopy

Nils Huse, Tae Kyu Kim, Munira Khalil, Lindsey Jamula, James K. McCusker, Robert W. Schoenlein

Department of Chemistry

Research output: Chapter in Book/Report/Conference proceeding › Chapter

Abstract

We report the first time-resolved soft x-ray measurements of solvated transitionmetal complexes. L-edge spectroscopy directly probes dynamic changes in ligand-field splitting of 3d orbitals associated with the spin transition, and mediated by changes in ligand-bonding.

Original language	English
Title of host publication	Springer Series in Chemical Physics
Publisher	Springer Science and Business Media Deutschland GmbH
Pages	125-127
Number of pages	3
DOIs	https://doi.org/10.1007/978-3-540-95946-5_41
Publication status	Published - 2009

Publication series

Name	Springer Series in Chemical Physics
Volume	92
ISSN (Print)	0172-6218

Bibliographical note

Publisher Copyright:
© 2009, Springer-Verlag Berlin Heidelberg.

All Science Journal Classification (ASJC) codes

Physical and Theoretical Chemistry

Access to Document

10.1007/978-3-540-95946-5_41

Cite this

Huse, N., Kim, T. K., Khalil, M., Jamula, L., McCusker, J. K., & Schoenlein, R. W. (2009). Probing Reaction Dynamics of Transition-Metal Complexes in Solution via Time-Resolved Soft X-ray Spectroscopy. In Springer Series in Chemical Physics (pp. 125-127). (Springer Series in Chemical Physics; Vol. 92). Springer Science and Business Media Deutschland GmbH. https://doi.org/10.1007/978-3-540-95946-5_41

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abstract = "We report the first time-resolved soft x-ray measurements of solvated transitionmetal complexes. L-edge spectroscopy directly probes dynamic changes in ligand-field splitting of 3d orbitals associated with the spin transition, and mediated by changes in ligand-bonding.",

keywords = "Local Chemical Bonding, Quantitative Fingerprint, Silicon Nitride Membrane, Spin Transition, Transient Absorption Change",

author = "Nils Huse and Kim, {Tae Kyu} and Munira Khalil and Lindsey Jamula and McCusker, {James K.} and Schoenlein, {Robert W.}",

note = "Publisher Copyright: {\textcopyright} 2009, Springer-Verlag Berlin Heidelberg.",

year = "2009",

doi = "10.1007/978-3-540-95946-5_41",

language = "English",

series = "Springer Series in Chemical Physics",

publisher = "Springer Science and Business Media Deutschland GmbH",

pages = "125--127",

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Huse, N, Kim, TK, Khalil, M, Jamula, L, McCusker, JK & Schoenlein, RW 2009, Probing Reaction Dynamics of Transition-Metal Complexes in Solution via Time-Resolved Soft X-ray Spectroscopy. in Springer Series in Chemical Physics. Springer Series in Chemical Physics, vol. 92, Springer Science and Business Media Deutschland GmbH, pp. 125-127. https://doi.org/10.1007/978-3-540-95946-5_41

Probing Reaction Dynamics of Transition-Metal Complexes in Solution via Time-Resolved Soft X-ray Spectroscopy. / Huse, Nils; Kim, Tae Kyu; Khalil, Munira et al.
Springer Series in Chemical Physics. Springer Science and Business Media Deutschland GmbH, 2009. p. 125-127 (Springer Series in Chemical Physics; Vol. 92).

Research output: Chapter in Book/Report/Conference proceeding › Chapter

TY - CHAP

T1 - Probing Reaction Dynamics of Transition-Metal Complexes in Solution via Time-Resolved Soft X-ray Spectroscopy

AU - Huse, Nils

AU - Kim, Tae Kyu

AU - Khalil, Munira

AU - Jamula, Lindsey

AU - McCusker, James K.

AU - Schoenlein, Robert W.

PY - 2009

Y1 - 2009

N2 - We report the first time-resolved soft x-ray measurements of solvated transitionmetal complexes. L-edge spectroscopy directly probes dynamic changes in ligand-field splitting of 3d orbitals associated with the spin transition, and mediated by changes in ligand-bonding.

AB - We report the first time-resolved soft x-ray measurements of solvated transitionmetal complexes. L-edge spectroscopy directly probes dynamic changes in ligand-field splitting of 3d orbitals associated with the spin transition, and mediated by changes in ligand-bonding.

KW - Local Chemical Bonding

KW - Quantitative Fingerprint

KW - Silicon Nitride Membrane

KW - Spin Transition

KW - Transient Absorption Change

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SP - 125

EP - 127

BT - Springer Series in Chemical Physics

PB - Springer Science and Business Media Deutschland GmbH

ER -

Probing Reaction Dynamics of Transition-Metal Complexes in Solution via Time-Resolved Soft X-ray Spectroscopy

Abstract

Publication series

Bibliographical note

All Science Journal Classification (ASJC) codes

Access to Document

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Cite this