Prereforming of n-tetradecane over Ce-promoted 50 wt% Ni/MgO-Al2O3 catalyst with high coke resistance

Sung Hun Lee, Kee Young Koo, Un Ho Jung, Yong Gun Shul, Wang Lai Yoon

Research output: Contribution to journalArticlepeer-review

1 Citation (Scopus)


The effect of Ce-promotion on 50 wt% Ni-based catalysts during the prereforming of n-tetradecane and its optimum content were investigated. The Ni catalyst was synthesized by deposition-precipitation method. Next, various amounts of Ce (0-13 wt%) were loaded on the Ni catalyst by impregnation. The characteristics of the prepared catalysts were analyzed by XRD, H2-TPR, BET, BJH, and H2-chemisorption analyses. The prepared catalysts were tested under the prereforming conditions (temperature = 400 °C, GHSV = 3000 h-1, and S/C = 3 and 4). The Ni catalyst was easily deactivated under the following conditions: temperature = 400 °C, GHSV = 3000 h-1, and S/C = 4. The stability of all Ce-promoted Ni catalysts was improved as compared to that of the Ni catalyst. Among the Ce-promoted catalysts, 5 wt% Ce/50 wt% Ni/MgO-Al2O3 catalyst showed excellent stability even under the severe condition of S/C = 3. SEM, TEM, and TG analyses were performed in order to identify the main factor responsible for the rapid deactivation of the Ni catalyst. In the case of 0Ce/50Ni, Ni particles were encapsulated by many folds of coke and it was related to the rapid catalyst deactivation. However, after Ce promoted on the Ni catalyst, the thickness of the coke layers and the number of encapsulated Ni particles decreased and the deposited amount of coke on the catalyst also decreased.

Original languageEnglish
Pages (from-to)237-248
Number of pages12
JournalResearch on Chemical Intermediates
Issue number1
Publication statusPublished - 2016 Jan 1

Bibliographical note

Publisher Copyright:
© 2015 Springer Science+Business Media Dordrecht.

All Science Journal Classification (ASJC) codes

  • General Chemistry


Dive into the research topics of 'Prereforming of n-tetradecane over Ce-promoted 50 wt% Ni/MgO-Al2O3 catalyst with high coke resistance'. Together they form a unique fingerprint.

Cite this