Positional Installation of Unsymmetrical Fluorine Functionalities onto Metal-Organic Frameworks for Efficient Carbon Dioxide Separation under Humid Conditions

Seongwoo Kim, Tae Ung Yoon, Kwang Hyun Oh, Jaesung Kwak, Youn Sang Bae, Min Kim

Research output: Contribution to journalArticlepeer-review

11 Citations (Scopus)

Abstract

Unsymmetrical trifluoro functional groups were installed onto metal-organic frameworks (MOFs) at positions regulated by ligand exchange for efficient CO2 separation under humid conditions. These trifluoro groups induced molecular separation via dipole-dipole interactions. Their installation onto amino-functionalized MOF surfaces produced hydrophobic and CO2-philic core-shell MOFs for efficient CO2 adsorption.

Original languageEnglish
Pages (from-to)18048-18054
Number of pages7
JournalInorganic Chemistry
Volume59
Issue number24
DOIs
Publication statusPublished - 2020 Dec 21

Bibliographical note

Publisher Copyright:
© 2020 American Chemical Society.

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

Fingerprint

Dive into the research topics of 'Positional Installation of Unsymmetrical Fluorine Functionalities onto Metal-Organic Frameworks for Efficient Carbon Dioxide Separation under Humid Conditions'. Together they form a unique fingerprint.

Cite this